3,3'-二甲基-4-(1,1'-联苯)胺合成路线 （共 4 条）
反应条件
1: AlCl3 / 1,2-dichloro-ethane
2: aq. Ca(OCl)2
3: SOCl2
4: aq. NH3
5: aq. KOH, Br2
View Scheme
参考文献
Dovgosheya,M.I.; Krasovitskii,B.M.
Zhurnal Organicheskoi Khimii, 1966 , vol. 2, # 7 p. 1288 - 1291,1286 - 1288
反应条件
hypophosphorous acid
Diazotization.aus monodiazotiertem 3,3'-Dimethyl-benzidin;
参考文献
Litwinenko et al.
Z.obs.Chim., 1957 , vol. 27, p. 3115,3121;engl.Ausg.S.3154,3158
反应条件
sodium tetrathionate in various solvent(s)
T=70°C; Reduction; pH=6; Product distribution; Further Variations:Reaction partners;
参考文献
Platzek; Lang; Grohmann; Gi; Baltes
Human and Experimental Toxicology, 1999 , vol. 18, # 9 p. 552 - 559
反应条件
1: aqueous HCl / Diazotization.Erwaermen des Reaktionsgemisches mit KI
2: copper-powder / 260 °C
View Scheme
参考文献
Kern et al.
Makromolekulare Chemie, 1959 , vol. 29, p. 164,178
Makromolekulare Chemie, 1959 , vol. 31, p. 154,163
