3-丁烯-1-炔-1-基苯合成路线 （共 40 条）
反应条件
1: Na2CO3 / H2O / 24 h / 25 °C
2: 82 percent / hexamethylphosphoric acid triamide / 250 °C
View Scheme
参考文献
Collins, Clair J.; Hanack, Michael; Stutz, Herbert; Auchter, Gerhard; Schoberth, Winfried
Journal of Organic Chemistry, 1983 , vol. 48, # 26 p. 5260 - 5268
反应条件
sodium carbonate in various solvent(s)
T=80°C; 288 h; Further byproducts given;
参考文献
Collins, Clair J.; Hanack, Michael; Stutz, Herbert; Auchter, Gerhard; Schoberth, Winfried
Journal of Organic Chemistry, 1983 , vol. 48, # 26 p. 5260 - 5268
反应条件
tetrabutyl ammonium fluoride; copper diacetate in 1,4-dioxane; dichloromethane
T=30°C;
参考文献
Arsenyan, Pavel; Petrenko, Alla; Paegle, Edgars; Belyakov, Sergey
Mendeleev Communications, 2011 , vol. 21, # 6 p. 326 - 328
反应条件
sodium carbonate in various solvent(s)
T=80°C; 288 h; Further byproducts given;
参考文献
Collins, Clair J.; Hanack, Michael; Stutz, Herbert; Auchter, Gerhard; Schoberth, Winfried
Journal of Organic Chemistry, 1983 , vol. 48, # 26 p. 5260 - 5268
反应条件
sodium carbonate in various solvent(s)
T=80°C; 288 h; Further byproducts given;
参考文献
Collins, Clair J.; Hanack, Michael; Stutz, Herbert; Auchter, Gerhard; Schoberth, Winfried
Journal of Organic Chemistry, 1983 , vol. 48, # 26 p. 5260 - 5268
反应条件
triethylamine in ethanol; water
T=25°C; 24 h; Further byproducts given;
参考文献
Collins, Clair J.; Hanack, Michael; Stutz, Herbert; Auchter, Gerhard; Schoberth, Winfried
Journal of Organic Chemistry, 1983 , vol. 48, # 26 p. 5260 - 5268
反应条件
sodium carbonate in water
T=25°C; 24 h; Further byproducts given;
参考文献
Collins, Clair J.; Hanack, Michael; Stutz, Herbert; Auchter, Gerhard; Schoberth, Winfried
Journal of Organic Chemistry, 1983 , vol. 48, # 26 p. 5260 - 5268
反应条件
1: 1.) Mg, ethyl bromide / 1.) THF, 1 h, reflux, 2.) 6 h, 0 deg C, 12 h, room temp.
2: 82 percent / hexamethylphosphoric acid triamide / 250 °C
View Scheme
参考文献
Collins, Clair J.; Hanack, Michael; Stutz, Herbert; Auchter, Gerhard; Schoberth, Winfried
Journal of Organic Chemistry, 1983 , vol. 48, # 26 p. 5260 - 5268
反应条件
potassium hydrogensulfate
T=200°C; P=0.8 Torr; Yield given;
参考文献
Hofmann, Joerg; Zimmermann, Gerhard; Homann, Klaus-Heinrich
Liebigs Annalen, 1995 , # 5 p. 841 - 848
反应条件
1: 1.) n-BuLi / 1.) THF, hexane, 2.) THF
2: methanol / 20 °C / Irradiation
View Scheme
参考文献
Krijnen, Erik S.; Zuilhof, Han; Lodder, Gerrit
Journal of Organic Chemistry, 1994 , vol. 59, # 26 p. 8139 - 8150
