2,2-二溴-1-苯乙酮合成路线 （共 82 条）
反应条件
mercury dichloride; zinc in diethyl ether; ethyl acetate
T=55 - 60°C; 0.5 h;
参考文献
Shchepin, V. V.; Gladkova, G. E.; Russkikh, N. Yu.
Journal of Organic Chemistry USSR (English Translation), 1992 , vol. 28, # 6.1 p. 902 - 907
Zhurnal Organicheskoi Khimii, 1992 , vol. 28, # 6 p. 1156 - 1162
反应条件
1: sodium acetate; diluted alcohol; hydroxylamine hydrochloride / 70 - 80 °C
2: diluted NaOH-solution
View Scheme
参考文献
Ponzio; Avogadro
Gazzetta Chimica Italiana, 1923 , vol. 53, p. 316
反应条件
sodium azide in water; acetone
Ambient temperature;
参考文献
Weber, Gunther; Hauptmann, Siegfried; Wilde, Horst; Mann, Gerhard
Synthesis, 1983 , # 3 p. 191 - 192
反应条件
1: α,α-dibromo-1-phenylethanone With dimethyl sulfoxide
T=70 - 75°C; Inert atmosphere;
2: cyclohexanol T=25 - 30°C; Inert atmosphere;
参考文献
Raghunadh, Akula; Meruva, Suresh Babu; Kumar, Nuka Anil; Kumar, Gudla Santosh; Rao, L. Vaikunta; Syamkumar
Synthesis, 2012 , vol. 2012, # 2 p. 283 - 289
反应条件
1: T=70 - 75°C; Inert atmosphere;
2: With sodium hydride
T=25 - 30°C; Inert atmosphere;
参考文献
Raghunadh, Akula; Meruva, Suresh Babu; Kumar, Nuka Anil; Kumar, Gudla Santosh; Rao, L. Vaikunta; Syamkumar
Synthesis, 2012 , vol. 2012, # 2 p. 283 - 289
参考文献
Cooper,D.J.; Owen,L.N.
Journal of the Chemical Society [Section] C: Organic, 1966 , p. 533 - 540
反应条件
ethanol; ether-mixture
参考文献
Kroehnke
Chemische Berichte, 1950 , vol. 83, p. 50,59
反应条件
iodine; copper in toluene
参考文献
Kawabata,N. et al.
Bulletin of the Chemical Society of Japan, 1977 , vol. 50, p. 1005 - 1006
反应条件
in tetrahydrofuran
air;
参考文献
Shanmugapriya; Shankar; Satyanarayana; Dahanukar, Vilas H.; Kumar, U. K. Syam; Vembu
Synlett, 2008 , # 19 p. 2945 - 2950
反应条件
carbon tetrabromide; water; oxygen
10 h; Irradiation;
参考文献
Yamaguchi, Tomoaki; Nobuta, Tomoya; Kudo, Yasuhisa; Hirashima, Shin-Ichi; Tada, Norihiro; Miura, Tsuyoshi; Itoh, Akichika
Synlett, 2013 , vol. 24, # 5 art. no. ST-2013-U0018-L, p. 607 - 610
