α-三甲基硅烷基乙烯基溴合成路线 （共 42 条）
反应条件
tetra-n-butylammonium tetrafluoroborate; NiBr2bipy in N,N-dimethyl-formamide T=-10°C; electrolysis with 3 F/mol at 10 mA/cm2; Pt cathode, Mg anode; without/with catalyst; Product distribution;
参考文献
Kamekawa, Hisato; Kudoh, Hiroki; Senboku, Hisanori; Tokuda, Masao
Chemistry Letters, 1997 , # 9 p. 917 - 918
反应条件
1: 1-bromo-1-trimethylsilylethene 2: dodecyl bromide With N,N,N',N,-tetramethylethylenediamine; iron(III) chloride in tetrahydrofuran T=0°C; 0.5 h; Further stages. Title compound not separated from byproducts.;
参考文献
Angewandte Chemie - International Edition, , vol. 46, # 34 p. 6521 - 6524
反应条件
potassium hydroxide; tetrakis(triphenylphosphine) palladium(0); tetrabutylammomium bromide in tetrahydrofuran 1.5 h; Heating;
参考文献
Heterocycles, , vol. 22, # 11 p. 2475 - 2478
反应条件
tetrakis(triphenylphosphine) palladium(0)
参考文献
Carpita, Adriano; Rossi, Renzo; Scamuzzi, Barbara
Tetrahedron Letters, 1989 , vol. 30, # 20 p. 2699 - 2702
反应条件
tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran
1 h; Heating; Product distribution;
参考文献
Ennis, David S.; Gilchrist, Thomas L.
Tetrahedron Letters, 1989 , vol. 30, # 28 p. 3735 - 3736
反应条件
Yield given. Multistep reaction;
参考文献
Ennis, David S.; Gilchrist, Thomas L.
Tetrahedron, 1990 , vol. 46, # 7 p. 2623 - 2632
反应条件
1: 75 percent / t-BuLi / diethyl ether; tetrahydrofuran / -78 °C
2: 1.) thexylborane; 2.) 2M NaOH, 30percent H2O2 / 1.) THF, 0 deg C -> r.t., 8 h
View Scheme
参考文献
Lipshutz, Bruce H.; Mollard, Paul; Lindsley, Craig; Chang, Virginia
Tetrahedron Letters, 1997 , vol. 38, # 11 p. 1873 - 1876
反应条件
1: 1-bromo-1-trimethylsilylethene
2: 4-phenoxy-1-butylbromide With N,N,N',N,-tetramethylethylenediamine; iron(III) chloride in tetrahydrofuran
T=0°C; 0.5 h; Further stages. Title compound not separated from byproducts.;
参考文献
Guerinot, Amandine; Reymond, Sebastien; Cossy, Janine
Angewandte Chemie - International Edition, 2007 , vol. 46, # 34 p. 6521 - 6524
反应条件
1: 1-bromo-1-trimethylsilylethene
2: 6-iodohexene With N,N,N',N,-tetramethylethylenediamine; iron(III) chloride in tetrahydrofuran
T=0°C; 0.5 h; Further stages. Title compound not separated from byproducts.;
参考文献
Guerinot, Amandine; Reymond, Sebastien; Cossy, Janine
Angewandte Chemie - International Edition, 2007 , vol. 46, # 34 p. 6521 - 6524
反应条件
1: 1-bromo-1-trimethylsilylethene
2: dodecyl bromide With N,N,N',N,-tetramethylethylenediamine; iron(III) chloride in tetrahydrofuran
T=0°C; 0.5 h; Further stages. Title compound not separated from byproducts.;
参考文献
Guerinot, Amandine; Reymond, Sebastien; Cossy, Janine
Angewandte Chemie - International Edition, 2007 , vol. 46, # 34 p. 6521 - 6524
