9,9-二甲基-9H-9-硅芴合成路线 （共 43 条）
反应条件
1.1: 54 percent / n-BuLi / diethyl ether; hexane / -78 °C
2.1: n-BuLi / diethyl ether; hexane / -78 - 20 °C
2.2: 94.1 percent / diethyl ether; hexane / -78 - 20 °C
View Scheme
参考文献
Liu; Stringfellow; Ballweg; Guzei; West
Journal of the American Chemical Society, 2002 , vol. 124, # 1 p. 49 - 57
反应条件
Wilkinson's catalyst in 1,4-dioxane
T=135°C; 1 h; Inert atmosphere;
参考文献
Ureshino, Tomonari; Yoshida, Takuya; Kuninobu, Yoichiro; Takai, Kazuhiko
Journal of the American Chemical Society, 2010 , vol. 132, # 41 p. 14324 - 14326
反应条件
1: 2,2'-dibromobiphenyl With tert.-butyl lithium in tetrahydrofuran; pentane
T=-75 - -60°C; 1 h;
2: allyl(chloro)dimethylsilane With triethylamine in tetrahydrofuran; pentane
T=20°C; 2 h;
参考文献
Hudrlik, Paul F.; Dai, Donghua; Hudrlik, Anne M.
Journal of Organometallic Chemistry, 2006 , vol. 691, # 6 p. 1257 - 1264
反应条件
in ethylene glycol dimethyl ether
T=20°C; 1 h;
参考文献
Chauvin, Yves; Marchal, Nathalie; Olivier, Helene; Saussine, Lucien
Journal of Organometallic Chemistry, 1993 , vol. 445, # 1.2 p. 93 - 97
反应条件
1: 2,2'-dibromobiphenyl With tert.-butyl lithium in tetrahydrofuran; pentane
T=-75 - -60°C; 1 h;
2: dimethyl(phenyl)silyl chloride With triethylamine in tetrahydrofuran; pentane
T=20°C; 1.25 h;
参考文献
Hudrlik, Paul F.; Dai, Donghua; Hudrlik, Anne M.
Journal of Organometallic Chemistry, 2006 , vol. 691, # 6 p. 1257 - 1264
反应条件
1: 2,2'-dibromobiphenyl With n-butyllithium in tetrahydrofuran; hexane
T=0°C;
2: chloro-trimethyl-silane in tetrahydrofuran; hexane
T=0°C;
参考文献
Nagaki, Aiichiro; Takabayashi, Naofumi; Tomida, Yutaka; Yoshida, Jun-ichi
Organic Letters, 2008 , vol. 10, # 18 p. 3937 - 3940
反应条件
palladium diacetate; diethylamine; 2-Mes-C6H4-PCy2
Inert atmosphere;
参考文献
Shimizu, Masaki; Mochida, Kenji; Hiyama, Tamejiro
Angewandte Chemie - International Edition, 2008 , vol. 47, # 50 p. 9760 - 9764
反应条件
1: 9.3 percent
2: benzene / Ambient temperature; Irradiation; var. solv.: hexane; add of 2,3-dimethylbutadiene
View Scheme
参考文献
Sakurai, Hideki; Sakamoto, Kenkichi; Kira, Mitsuo
Chemistry Letters, 1984 , p. 1379 - 1382
反应条件
1: in tetrahydrofuran
T=0°C; 0.5 h;
2: With water in tetrahydrofuran
T=0 - 20°C; 1 h;
参考文献
Lillo, Victor J.; Gomez, Cecilia; Yus, Miguel
Tetrahedron Letters, 2009 , vol. 50, # 19 p. 2266 - 2269
反应条件
in tetrahydrofuran; diethyl ether
T=-78°C;
参考文献
Ishikawa, Mitsuo; Nishimura, Kunio; Sugisawa, Hiroshi; Kumada, Makoto
Journal of Organometallic Chemistry, 1981 , vol. 218, # 2 p. C21 - C24
