9,9-二甲基-9H-9-硅芴合成路线 （共 43 条）
参考文献
Gilman; Gorsich
Journal of the American Chemical Society, 1958 , vol. 80, p. 3243,3244
反应条件
1: ortho-dibromobenzene With tert.-butyl lithium in tetrahydrofuran; diethyl ether; pentane
T=-120 - 20°C; 0.666667 h;
2: trimethylsilyl trifluoromethanesulfonate in tetrahydrofuran; diethyl ether; pentane
T=-120 - -110°C; 0.5 h; Further stages. Further byproducts.;
参考文献
Bettinger, Holger F.; Filthaus, Matthias
Journal of Organic Chemistry, 2007 , vol. 72, # 25 p. 9750 - 9752
反应条件
in hexane
1 h; Ambient temperatureIrradiation;
参考文献
Sakurai, Hideki; Sakamoto, Kenkichi; Kira, Mitsuo
Chemistry Letters, 1984 , p. 1379 - 1382
反应条件
ethenetetracarbonitrile in tetrachloromethane; dichloromethane
Ambient temperatureIrradiationirradiation (589 nm); var.: without CCl4;
参考文献
Sakurai, Hideki; Sakamoto, Kenkichi; Kira, Mitsuo
Chemistry Letters, 1984 , p. 1213 - 1214
反应条件
1: 1.) n-BuLi / 1.) ether, hexane, RT, 3 h, 2.) ether, hexane, reflux, 3 h
2: 100 percent Chromat. / diethyl ether; tetrahydrofuran / 1 h / Ambient temperature
View Scheme
参考文献
Ishikawa, Mitsuo; Tabohashi, Tatsuru; Sugisawa, Hiroshi; Nishimura, Kunio; Kumada, Makoto
Journal of Organometallic Chemistry, 1983 , vol. 250, # 1 p. 109 - 120
反应条件
in benzene
5 h; Irradiation;
参考文献
Kira,M.; Sakamoto,K.; Sakurai,H.
Journal of the American Chemical Society, 1983 , vol. 105, p. 7469
反应条件
Wilkinson's catalyst in 1,4-dioxane
T=135°C; 0.0125 h;
参考文献
Ureshino, Tomonari; Yoshida, Takuya; Kuninobu, Yoichiro; Takai, Kazuhiko
Journal of the American Chemical Society, 2010 , vol. 132, # 41 p. 14324 - 14326
反应条件
1,4-diaza-bicyclo[2.2.2]octane; [RhCl(η2:η2-cycloocta-1,5-diene)]2
T=160°C; 15 h;
参考文献
Onoe, Masahiro; Baba, Katsuaki; Kim, Yoonjoo; Kita, Yusuke; Tobisu, Mamoru; Chatani, Naoto
Journal of the American Chemical Society, 2012 , vol. 134, # 47 p. 19477 - 19488
反应条件
1: 71 percent / n-Buli / 2.5 h / -78 - -75 °C
2: 1.) Mg powder / 1.) iodine / 1.) THF, 6 h, 2.) THF, r.t.
View Scheme
参考文献
Corey, Joyce Y.; Chang, Lihsueh S.
Journal of Organometallic Chemistry, 1986 , vol. 307, p. 7 - 14
参考文献
Kira,M.; Sakamoto,K.; Sakurai,H.
Journal of the American Chemical Society, 1983 , vol. 105, p. 7469
