(±)-2-甲基-1-丁醇合成路线 （共 128 条）
反应条件
hydrogen; CoRh; iodine T=200°C; P=420 Torr; 2 h; other promoter, other pressure; Product distribution;
参考文献
Journal of Organometallic Chemistry, , vol. 346, p. 237 - 252
反应条件
Fischer-Tropsch cobalt contact; hydrogen T=120 - 160°C; P=73550.8 - 147102 Torr; folgende Hydrierung am gleichen Katalysator;
参考文献
Recueil des Travaux Chimiques des Pays-Bas, , vol. 67, p. 302
反应条件
nickel T=80°C; Hydrogenation.unter Druck;
反应条件
1: sulfuric acid / 24 h / |Reflux; |Inert atmosphere 2: [Ir(cod)Py(3)]+[BArF]-; hydrogen / dichloromethane / 1500.15 Torr / |Inert atmosphere 3: lithium aluminium tetrahydride / |Inert atmosphere View Scheme
参考文献
Chemistry - A European Journal, , vol. 18, # 34 p. 10609 - 10616
反应条件
hydrogen; H4Ru4(CO)8lt;P(CH2OCO-(S)-C2H5CH(CH3))3gt;4 in neat (no solvent) T=150°C; 48 h; p(H2) 130 atm at 20 deg C; other time and temperature, further Ru catalyst; Product distributionMechanism;
参考文献
Journal of Organometallic Chemistry, , vol. 582, # 2 p. 218 - 228
反应条件
hydrogenchloride; Ni(PPh3)2 1) room temp., 50 h; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Chemistry Letters, , p. 219 - 222
反应条件
sodium tetrahydroborate; hydrogen; [Rhacetylacetonate(1,5-cyclooctadiene)]; phosphite 4a autoclave, 1.) PhH, 70 deg C, 8 h; 2.) THF/H2O, 0 deg C, 1 h; Yield given. Multistep reaction;
参考文献
Helvetica Chimica Acta, , vol. 76, p. 2654 - 2665
反应条件
Me2S*BH2Cl; dihydrogen peroxide Other Boron compounds used.;
参考文献
Journal of Organic Chemistry, , vol. 45, # 22 p. 4540 - 4542
反应条件
T=250°C; P=110326 - 202265 Torr; Racemisierung.Hydrogenation;
参考文献
Journal of the American Chemical Society, , vol. 56, p. 689
反应条件
1: CO, methylviologene / H2O / 40 °C / pH: 7.5-8; Clostridium thermoaceticum 2: CO, methylviologene / H2O / 40 °C / pH: 5.5; Clostridium thermoaceticum View Scheme
参考文献
Angewandte Chemie, , vol. 99, # 8 p. 785 - 787
