1,1,2,2-四氯-二硼烷合成路线 （共 63 条）
反应条件
byproducts: ClNH2(CH3)C2H4(CH3)NH2Cl; molar ratio of B2Cl4 and amine = 1:4;
参考文献
Welch; Shore
Inorganic Chemistry, 1968 , vol. 7, p. 225,226, 227, 230
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Gmelin Handbook: B: B-Verb.1, 2.5.2.2, page 130 - 132
反应条件
in neat (no solvent) byproducts: CBr3Cl; heating of B2F4 and CFBr3 in a sealed tube at 130°C for 2,5 h; fractionation at -160 and -95°C yielded B2F4;
参考文献
Saulys, D. A; Castillo, J.; Morrison, J. A.
Inorganic Chemistry, 1989 , vol. 28, p. 1619 - 1624
反应条件
in monofluoro-trichloromethane B2Cl4 and 11-fold excess CCl3F were heated in a sealed tube at 65°C for 597 h; products detected by (19)F- and (11)B-NMR;
参考文献
Saulys, D. A; Castillo, J.; Morrison, J. A.
Inorganic Chemistry, 1989 , vol. 28, p. 1619 - 1624
反应条件
hexamethylbenzene and an addition product obtained, saponification of latter gives cis-2-butene;
参考文献
Gmelin Handbook: B: B-Verb.9, 4.2.4.4, page 128 - 130
参考文献
Gmelin Handbook: B: B-Verb.9, 4.2.4.4, page 128 - 130
反应条件
metal boron hydride byproducts: higher boranes;
参考文献
Journal of the American Chemical Society, , vol. 71, p. 3265 - 3266
B: SVol.1, 4.1.3, page 104 - 109
反应条件
highest HBCl2 yield at 15 min;
参考文献
Inorganic Chemistry, , vol. 9, p. 1661,1664
B: B-Verb.9, 1.2.2.1, page 15 - 20
反应条件
in neat (no solvent) reaction carried out in Pyrex tubes to which Teflon valves had been sealed or in a N2-filled glovebox; reaction of B2Cl4 with excess B5H9 in a 1:3 mole ratio; vessel allowed to warm from -196 ° C to ambient temp., 20 min at ambient temp.,; fractionation, yield of 1-BCl2B5H8 based upon amt. of B2Cl4 employed: 73percent, based upon amt. of B5H9 consumed: 95percent; small amts. of B2H6, BCl2H, B2H5Cl, also material insufficiently volatileto move into vac. line formed;;
参考文献
Inorganic Chemistry, , vol. 29, p. 4174 - 4179
参考文献
Journal of the American Chemical Society, , vol. 71, p. 3265 - 3266
反应条件
room temp.; B2H5Cl detected by IR spectroscopy after 22.5 h;
参考文献
B: B-Verb.9, 2.1.2.1, page 45 - 47
Diss. Abstr., Thesis Pennsylvania State Univ. 1961 , vol. 22, p. 86/7
