1,1,2,2-四氯-二硼烷合成路线 （共 63 条）
反应条件
stable HBCl2/BCl3 mixt. obtained after fracti onation of react. mixt. in cold traps, HBCl2/BCl3 mixt. trapped at -112°C;
参考文献
Inorganic Chemistry, , vol. 9, p. 1661,1664
B: B-Verb.9, 1.2.2.1, page 15 - 20
反应条件
in neat (no solvent) reaction of NMe4Cl and B2Cl4 at -196°C, warming up to 0°C;
参考文献
Zeitschrift fuer Anorganische und Allgemeine Chemie, , vol. 592, p. 35 - 41
反应条件
in chloroform-d1 under N2, with exclusion of moisture, condensed reagents (1/1 or 1.14/0.55 mmol ratio) gently warmed to room temp.; not sepd.; detected by NMR, IR;
参考文献
Chemische Berichte, , vol. 113, # 7 p. 2333 - 2341
反应条件
in chloroform-d1 under N2, with exclusion of moisture, condensation of reagents in 1.14/0.55 mmol ratio, gently warmed to room temp.; not sepd.; detected by NMR, IR;
参考文献
Chemische Berichte, , vol. 113, # 7 p. 2333 - 2341
反应条件
under N2, with exclusion of moisture, reagents in 8/4.4 mmol ratio, condensed at -196°C, gently warmed to room temp. for 15 min; BCl3 sepd. by distn.; elem. anal.;
参考文献
Chemische Berichte, , vol. 113, # 7 p. 2333 - 2341
反应条件
room temp.; B2H5Cl detected by IR spectroscopy after 22.5 h;
参考文献
B: B-Verb.9, 2.1.2.1, page 45 - 47
Diss. Abstr., Thesis Pennsylvania State Univ. 1961 , vol. 22, p. 86/7
反应条件
compn. of gas phase final product studied by IR spectroscopy;
参考文献
B: B-Verb.9, 2.1.2.1, page 45 - 47
Diss. Abstr., Thesis Pennsylvania State Univ. 1961 , vol. 22, p. 86/7
反应条件
excess of (CH3)2BN(CH3);
参考文献
Gmelin Handbook: B: B-Verb.4, 4.9.3, page 181 - 204
反应条件
HCl (liquid) in further solvent(s) reaction of a mixt. of PCl5 and B2Cl4 (2:1) in liquid HCl at -196°C; (11)B and (31)P NMR at 0°C;
参考文献
Haubold, W.; Kraatz, U.; Einholz, W.
Zeitschrift fuer Anorganische und Allgemeine Chemie, 1991 , vol. 592, p. 35 - 41
参考文献
Coyle, T. D.; Ritter, J. J.
Advan. Organomatal. Chem., 1972 , vol. 10, p. 237 - 272
Full Text Show Details
Gmelin Handbook: B: B-Verb.9, 4.2.4.4, page 128 - 130
