sodium cyanoborohydride in water; acetonitrile 0.25 h;

sodium cyanoborohydride in water; acetonitrile 0.25 h;

1: 33 percent / rhodium(II) octanoate / hexane / 1.5 h / Heating 2: 95 percent / H2 / RhCl(PPh3)3 / ethanol / 12 h / 2327.2 Torr 3: trifluoroacetic acid / CH2Cl2 / 0.5 h / Ambient temperature 4: sodium cyanoborohydride / H2O; acetonitrile / 0.25 h View Scheme

1: 95 percent / H2 / RhCl(PPh3)3 / ethanol / 12 h / 2327.2 Torr 2: trifluoroacetic acid / CH2Cl2 / 0.5 h / Ambient temperature 3: sodium cyanoborohydride / H2O; acetonitrile / 0.25 h View Scheme

1: 66 percent / dodecylbenzylsulfonyl azide, DBU / pentane / 0.13 h / 0 °C 2: 73 percent / rhodium(II) octanoate / toluene / 12 h / Heating 3: 96 percent / hydrogen / RhCl(PPh3)3 / ethanol / 12 h / 2327.2 Torr 4: 75 percent / tetrabutylammonium fluoride / tetrahydrofuran / 12 h / Ambient temperature 5: 97 percent / sodium cyanoborohydride / acetonitrile; H2O / 0.25 h View Scheme

1: 73 percent / rhodium(II) octanoate / toluene / 12 h / Heating 2: 96 percent / hydrogen / RhCl(PPh3)3 / ethanol / 12 h / 2327.2 Torr 3: 75 percent / tetrabutylammonium fluoride / tetrahydrofuran / 12 h / Ambient temperature 4: 97 percent / sodium cyanoborohydride / acetonitrile; H2O / 0.25 h View Scheme

1: 96 percent / hydrogen / RhCl(PPh3)3 / ethanol / 12 h / 2327.2 Torr 2: 75 percent / tetrabutylammonium fluoride / tetrahydrofuran / 12 h / Ambient temperature 3: 97 percent / sodium cyanoborohydride / acetonitrile; H2O / 0.25 h View Scheme

1: trifluoroacetic acid / CH2Cl2 / 0.5 h / Ambient temperature 2: sodium cyanoborohydride / H2O; acetonitrile / 0.25 h View Scheme

1: Mg / methanol / 0.67 h / sonication 2: 90 percent / Na(CN)BH3 / acetonitrile; H2O / 0.25 h View Scheme

1: 87 percent / t-BuOK / tetrahydrofuran / 0.92 h / 20 °C 2: 63 percent / Me3SiOTf / CH2Cl2 / 19 h / -78 - 20 °C 3: Mg / methanol / 0.67 h / sonication 4: 90 percent / Na(CN)BH3 / acetonitrile; H2O / 0.25 h View Scheme