1-苯基-1-三甲基甲硅氧基乙烯合成路线 （共 431 条）
反应条件
BnNMe3(+)F(-) in tetrahydrofuran 16 h; Ambient temperature;
参考文献
Hirsch, Elisabeth; Huenig, Siegfried; Reissig, Hans-Ulrich
Chemische Berichte, 1982 , vol. 115, # 12 p. 3687 - 3696
反应条件
1: With potassium hydroxide; ammonium cerium(IV) nitrate in methanol T=-78°C; Alkylation; dimerization; cyclization; 0.25 h; 2: With triethylamine in methanol T=20°C; Elimination; 0.333333 h;
参考文献
Bulletin of the Chemical Society of Japan, , vol. 70, # 10 p. 2525 - 2534
反应条件
indium(III) chloride in water-d2 Condensation; Mannich reaction; 7 h;
参考文献
Tetrahedron, , vol. 56, # 20 p. 3227 - 3237
反应条件
18-crown-6 ether; PhIO(1+)*BF4(1-)*18-crown-6 T=-78 - 20°C; 3.5 h;
参考文献
Sato, Saeko; Yoshida, Masanori; Hara, Shoji
Synthesis, 2005 , # 15 art. no. F18704SS, p. 2602 - 2605
反应条件
lead(IV) acetate in tetrahydrofuran; dichloromethane T=-78 - -25°C; 2.5 h; 1) -78 degC, 1.5h 2) R.T., 1h;
参考文献
Moriarty, Robert M.; Penmasta, Raju; Prakash, Indra
Tetrahedron Letters, 1987 , vol. 28, # 8 p. 873 - 876
反应条件
C6H6BF4IO*C12H24O6 in dichloromethane T=-78 - 20°C; 3.5 h; Inert atmosphere; Reagent/catalyst;
参考文献
Miyamoto, Kazunori; Yokota, Yukie; Suefuji, Takashi; Yamaguchi, Kentaro; Ozawa, Tomoyuki; Ochiai, Masahito
Chemistry - A European Journal, 2014 , vol. 20, # 18 p. 5447 - 5453
反应条件
[VO(OEt)Cl2] in dichloromethane 1) -75 deg C, 3 h, 2) -30 deg C, 4 h;
参考文献
Fujii Takashi; Hirao, Toshikazu; Ohshiro, Yoshiki
Tetrahedron Letters, 1992 , vol. 33, # 39 p. 5823 - 5826
反应条件
(PyCOO)3Mn in N,N-dimethyl-formamide Ambient temperature; Yields of byproduct given;
参考文献
Narasaka, Koichi; Miyoshi, Norikazu; Iwakura, Kazunori; Okauchi, Tatsuo
Chemistry Letters, 1989 , p. 2169 - 2172
反应条件
1: With potassium hydroxide; ammonium cerium(IV) nitrate in methanol T=-45°C; Alkylation; dimerization; 0.25 h; 2: With triethylamine in methanol T=20°C; Elimination; 0.333333 h;
参考文献
Arai, Noriyoshi; Narasaka, Koichi
Bulletin of the Chemical Society of Japan, 1997 , vol. 70, # 10 p. 2525 - 2534
反应条件
1: With potassium hydroxide; ammonium cerium(IV) nitrate in methanol T=-78°C; Alkylation; dimerization; cyclization; 0.25 h; 2: With triethylamine in methanol T=20°C; Elimination; 0.333333 h;
参考文献
Arai, Noriyoshi; Narasaka, Koichi
Bulletin of the Chemical Society of Japan, 1997 , vol. 70, # 10 p. 2525 - 2534
