1-苯基-1-三甲基甲硅氧基乙烯合成路线 （共 431 条）
反应条件
1: 1.) CsF, 2.) H2O / 1.) 25 deg C, 45 min, 25 deg C 2: 1.) CsF, 2.) H2O / 1.) 50 deg C, 30 min View Scheme
参考文献
Boyer, J.; Corriu, R. J. P.; Perz, R.; Reye, C.
Journal of Organometallic Chemistry, 1980 , vol. 184, # 2 p. 157 - 166
反应条件
water; cesium fluoride 1.) 50 deg C, 30 min; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Boyer, J.; Corriu, R. J. P.; Perz, R.; Reye, C.
Journal of Organometallic Chemistry, 1980 , vol. 184, # 2 p. 157 - 166
参考文献
Toray Industries, Inc.
Patent: US6215016 B1, 2001 ;
反应条件
potassium fluoride in dichloromethane 16 h; Heating; Yield given;
参考文献
Tokitoh, Norihiro; Okazaki, Renji
Bulletin of the Chemical Society of Japan, 1988 , vol. 61, # 3 p. 735 - 740
反应条件
Ph3C+ClO4- in dichloromethane T=-78°C;
参考文献
Kobayashi, Shu; Mukaiyama, Teruaki
Chemistry Letters, 1987 , p. 1183 - 1186
反应条件
tert-butyl hypofluorite in chloroform T=0°C; 0.666667 h;
参考文献
Journal of Organic Chemistry, , vol. 63, # 14 p. 4632 - 4635
反应条件
in chloroform T=0°C; 0.666667 h;
参考文献
Journal of Organic Chemistry, , vol. 63, # 14 p. 4632 - 4635
反应条件
1: lithium ethanolate; 2-Carboxybenzaldehyde in tetrahydrofuran 2: [(1-phenyl-1-ethenyl)oxy]trimethylsilane in N,N-dimethyl-formamide T=20°C; 2 h; 3: With hydrogenchloride in tetrahydrofuran T=20°C;
参考文献
Nakagawa, Takashi; Fujisawa, Hidehiko; Mukaiyama, Teruaki
Chemistry Letters, 2004 , vol. 33, # 2 p. 92 - 93
反应条件
trifluoromethyl hypofluorite in various solvent(s) T=-70°C; Yield given;
参考文献
Journal of the American Chemical Society, , vol. 102, # 14 p. 4845 - 4846
反应条件
fluorine in various solvent(s) T=-78°C; 3.5 h;
参考文献
Tetrahedron Letters, , vol. 27, # 24 p. 2715 - 2716
