1-苯基-1-三甲基甲硅氧基乙烯合成路线 （共 431 条）
反应条件
[Rh(I)(cycloocta-1,5-diene)(butane-1,4-diylbis[diphenylphosphine])]ClO4 in dichloromethane T=100°C; 17 h;
参考文献
Sato, Susumu; Matsuda, Isamu; Izumi, Yusuke
Journal of Organometallic Chemistry, 1988 , vol. 352, p. 223 - 238
反应条件
1: 1.) MeLi / 1.) THF, ether, 0 deg C, 30 min, 2.) THF, ether, CH2Cl2, hexane, -78 deg C, 0.5 h 2: 83 percent / 1,3,5-trimethyl-benzene / 7.5 h / Heating View Scheme
参考文献
Maruoka, Keiji; Concepcion, Arnel B.; Murase, Noriaki; Oishi, Masataka; Hirayama, Naoki; Yamamoto, Hisashi
Journal of the American Chemical Society, 1993 , vol. 115, # 10 p. 3943 - 3949
反应条件
1: SnCl4 / 1 h / -78 °C 2: mCPBA / CH2Cl2 / 0.5 h / -50 °C 3: NaHCO3 / 1,3,5-trimethyl-benzene / Heating 4: 59 percent / ZnCl2 / trifluoroacetic acid; H2O / 1 h / Ambient temperature View Scheme
参考文献
Sato, Tsuneo; Inoue, Masami; Kobara, Satoru; Otera, Junzo; Nozaki, Hitosi
Tetrahedron Letters, 1989 , vol. 30, # 1 p. 91 - 94
反应条件
(p-bromophenylimido)vanadium(V) trichloride in dichloromethane T=-85 - -15°C; 6 h; Inert atmosphere;
参考文献
Nishina, Masafumi; Moriuchi, Toshiyuki; Hirao, Toshikazu
Dalton Transactions, 2010 , vol. 39, # 41 p. 9936 - 9940
反应条件
RhCl(PPh3)3 in 1,4-dioxane 24 h; Heating;
参考文献
Sato, Kazuyuki; Higashinagata, Makoto; Yuki, Takashi; Tarui, Atsushi; Omote, Masaaki; Kumadaki, Itsumaro; Ando, Akira
Journal of Fluorine Chemistry, 2008 , vol. 129, # 1 p. 51 - 55
反应条件
1: 56 percent / SnCl4 / tetrahydrofuran / -35 - -30 °C 2: 85 percent / pyridine, methyl chlorosulfite / tetrahydrofuran / 36 h View Scheme
参考文献
Umemoto, Teruo; Kuriu, Yuriko; Nakayama, Shin-ichi; Miyano, Osamu
Tetrahedron Letters, 1982 , vol. 23, # 14 p. 1471 - 1474
反应条件
1: With lithium boron tetrafluoride; [Ru(2,2′-bipyridine)3][hexafluorophosphate]2; 2,3,5,6-tetramethyl-p-benzoquinone in aceonitrile T=20°C; 12 h; Inert atmosphereIrradiationMolecular sieve; 2: With water; ammonium chloride in acetonitrile T=20°C; 1 h; Inert atmosphereMolecular sieve;
参考文献
Yasu, Yusuke; Koike, Takashi; Akita, Munetaka
Chemical Communications, 2012 , vol. 48, # 43 p. 5355 - 5357
反应条件
[VO(OEt)Cl2] in dichloromethane 1) -75 deg C, 3 h, 2) -30 deg C, 4 h;
参考文献
Fujii Takashi; Hirao, Toshikazu; Ohshiro, Yoshiki
Tetrahedron Letters, 1992 , vol. 33, # 39 p. 5823 - 5826
反应条件
1: CH2Cl2 / -78 °C 2: 50 percent / CH2Cl2 / 0.17 h / Ambient temperature View Scheme
参考文献
Zhdankin, Viktor V.; Mullikin, Michelle; Tykwinski, Rik; Berglund, Bruce; Caple, Ronald; et al.
Journal of Organic Chemistry, 1989 , vol. 54, # 11 p. 2605 - 2608
反应条件
titanium tetrachloride in dichloromethane T=-78°C;
参考文献
Chan,T.H. et al.
Tetrahedron Letters, 1977 , # 48 p. 4183 - 4186
