1-苯基-1-三甲基甲硅氧基乙烯合成路线 （共 431 条）
反应条件
1: Cu(2,9-bis(p-anisyl)-1,10-phenanthroline)2Cl / acetonitrile / 12 h / |Inert atmosphere; |Irradiation
2: 5 palladium on charcoal; hydrogen / ethanol / 20 °C
View Scheme
参考文献
Paria, Suva; Pirtsch, Michael; Kais, Viktor; Reiser, Oliver
Synthesis (Germany), 2013 , vol. 45, # 19 art. no. 9872, p. 2689 - 2698
反应条件
boron trifluoride diethyl etherate in dichloromethane
T=-78°C; parallel recognition; 5 h;
参考文献
Chen, Jian-Xie; Sakamoto, Katsumasa; Orita, Akihiro; Otera, Junzo
Tetrahedron, 1998 , vol. 54, # 29 p. 8411 - 8420
反应条件
titanium tetrachloride in dichloromethane
T=-78°C; parallel recognition; 5 h;
参考文献
Chen, Jian-Xie; Sakamoto, Katsumasa; Orita, Akihiro; Otera, Junzo
Tetrahedron, 1998 , vol. 54, # 29 p. 8411 - 8420
反应条件
acetyl chloride; tin(ll) chloride in dichloromethane
12 h; Ambient temperature;
参考文献
Oriyama, Takeshi; Iwanami, Katsuyuki; Miyauchi,Yuka; Koga, Gen
Bulletin of the Chemical Society of Japan, 1990 , vol. 63, # 12 p. 3716 - 3718
反应条件
1: With boron trifluoride diethyl etherate in dichloromethane
T=-78 - 20°C;
2: With hydrogenchloride; water in dichloromethane
3: With toluene-4-sulfonic acid in toluene
T=40°C; 4 h;
参考文献
Rana, Nirmal K.; Selvakumar, Sermadurai; Singh, Vinod K.
Journal of Organic Chemistry, 2010 , vol. 75, # 6 p. 2089 - 2091
反应条件
titanium tetrachloride
1) CH2Cl2, -78 deg C, 15 min, 2) CH2Cl2, a) -78 deg C, 3 h, b) to r.t.; Yield given. Multistep reaction;
参考文献
Chan, T. H.; Nwe, K. T.
Journal of Organic Chemistry, 1992 , vol. 57, # 23 p. 6107 - 6111
反应条件
bis-(trifluoromethylsulphonyl)amine in dichloromethane
T=-78°C; Mukaiyama cross-aldol reaction; 2 h;
参考文献
Cossy; Lutz; Alauze; Meyer
Synlett, 2002 , # 1 p. 45 - 48
反应条件
trimethylsilyl trifluoromethanesulfonate in acetonitrile
T=-30 - 20°C; 0.166667 h;
参考文献
Matsugi; Murata; Gotanda; Nambu; Anilkumar; Matsumoto; Kita
Journal of Organic Chemistry, 2001 , vol. 66, # 7 p. 2434 - 2441
反应条件
trimethylsilyl trifluoromethanesulfonate in acetonitrile
0.166667 h; Yields of byproduct given;
参考文献
Matsugi, Masato; Gotanda, Kentoku; Murata, Kenji; Kita, Yasuyuki
Chemical Communications, 1997 , # 15 p. 1387 - 1388
反应条件
potassium carbonate; bis(η3-allyl-μ-chloropalladium(II)); Tedicyp in N,N-dimethyl-formamide
T=130°C; Heck reaction; 20 h;
参考文献
Battace, Ahmed; Feuerstein, Marie; Lemhadri, Mhamed; Zair, Touriya; Doucet, Henri; Santelli, Maurice
European Journal of Organic Chemistry, 2007 , # 19 p. 3122 - 3132
