1-苯基-1-三甲基甲硅氧基乙烯合成路线 （共 431 条）
反应条件
1: 90 percent / CH2Cl2
2: 91 percent / aq. HCl / methanol / 4 h / Ambient temperature
View Scheme
参考文献
Burger, Klaus; Helmreich, Brigitte
Journal fuer Praktische Chemie/Chemiker-Zeitung, 1992 , vol. 334, # 3 p. 219 - 226
反应条件
1: With trifluorormethanesulfonic acid in acetonitrile
T=20°C; 3 h;
2: With manganese triacetate in acetic acid; acetonitrile
T=20°C; 24 h;
参考文献
Akiyama, Takahiko; Nakashima, Saeko; Yokota, Koji; Fuchibe, Kohei
Chemistry Letters, 2004 , vol. 33, # 7 p. 922 - 923
反应条件
iodine in methanol
T=20°C; 0.5 h;
参考文献
Gu, Yanlong; Ogawa, Chikako; Kobayashi, Juta; Mori, Yuichiro; Kobayashi, Shu
Angewandte Chemie - International Edition, 2006 , vol. 45, # 43 p. 7217 - 7220
反应条件
boron trifluoride diethyl etherate; water in acetonitrile
T=0°C; Condensation; Mannich reaction; 1 h;
参考文献
x
Tetrahedron, 2002 , vol. 58, # 5 p. 983 - 988
反应条件
sodium tetrakis(3,5-trifluoromethylphenyl)borate in water
T=30°C; Mannich reaction; 1 h;
参考文献
Chang, Chi-Tsing; Liao, Bei-Sih; Liu, Shiuh-Tzung
Tetrahedron Letters, 2006 , vol. 47, # 52 p. 9257 - 9259
反应条件
indium(III) chloride in water-d2
Condensation; Mannich reaction; 7 h;
参考文献
Loh, Teck-Peng; Liung, Sarah B. K. W.; Tan, Kee-Leng; Wei, Lin-Li
Tetrahedron, 2000 , vol. 56, # 20 p. 3227 - 3237
反应条件
trimethylsilyl trifluoromethanesulfonate in dichloromethane
1.) -78 deg C, 15 min 2.) room temperature, 30 min;
参考文献
Attrill; Barrett; Quayle; et al.
Journal of Organic Chemistry, 1984 , vol. 49, # 10 p. 1679 - 1682
反应条件
zinc(II) iodide in dichloromethane
2 h; Ambient temperature;
参考文献
Reider; Rayford; Grabowski
Tetrahedron Letters, 1982 , vol. 23, # 4 p. 379 - 382
反应条件
in diethylene glycol dimethyl ether
T=180°C; 1 h; Inert atmosphere;
参考文献
Amii, Hideki; Oshiro, Kojun; Morimoto, Yoshimichi; Matsuura, Makoto
Patent: US2012/277458 A1, 2012 ;
Location in patent: Page/Page column 10 ;
反应条件
1: n-butyllithium / diethyl ether; hexane / -40 - -30 °C
2: xylene / 5 h / Heating
View Scheme
参考文献
Blanco, Luis; Amice, Philippe; Conia, Jean-Marie
Synthesis, 1981 , # 4 p. 291 - 293
