1-苯基-1-三甲基甲硅氧基乙烯合成路线 （共 431 条）
反应条件
1: 2-nitro-benzaldehyde With N,N-bis(perfluoromethanesulfonyl)squaramide in acetonitrile
T=20°C; 0.166667 h; Inert atmosphere;
2: [(1-phenyl-1-ethenyl)oxy]trimethylsilane in acetonitrile
T=20°C; Mukaiyama aldol reaction; 2 h; Inert atmosphere;
3: With hydrogenchloride; water
T=20°C; Mukaiyama aldol reaction; 0.5 h; Inert atmosphere;
参考文献
Li, Ningbo; Zhang, Xiaohong; Xu, Xinhua; Chen, Yun; Qiu, Renhua; Chen, Jinyang; Wang, Xie; Yin, Shuang-Feng
Advanced Synthesis and Catalysis, 2013 , vol. 355, # 11-12 p. 2430 - 2440
反应条件
triethylaluminum in hexane
Ambient temperature;
参考文献
Maruoka, Keiji; Fukutani, Yoshimi; Yamamoto, Hisashi
Journal of Organic Chemistry, 1985 , vol. 50, # 22 p. 4412 - 4414
反应条件
(CF3SO2)2NSiMe3 in dichloromethane
T=20°C; Sakurai-Hosomi allylation; 0.25 h;
参考文献
Ishihara; Hiraiwa; Yamamoto
Synlett, 2001 , # 12 p. 1851 - 1854
反应条件
potassium carbonate; bis(η3-allyl-μ-chloropalladium(II)); Tedicyp in N,N-dimethyl-formamide
T=130°C; Heck reaction; 20 h;
参考文献
Battace, Ahmed; Feuerstein, Marie; Lemhadri, Mhamed; Zair, Touriya; Doucet, Henri; Santelli, Maurice
European Journal of Organic Chemistry, 2007 , # 19 p. 3122 - 3132
反应条件
1: ammonium hexanitratocerate(IV); KOH / methanol / 0.25 h / -78 °C
2: DBU / CH2Cl2 / 20 °C
View Scheme
参考文献
Arai, Noriyoshi; Narasaka, Koichi
Chemistry Letters, 1995 , # 11 p. 987 - 988
反应条件
trimethylsilyl cyanide; [RhCl(η2:η2-cycloocta-1,5-diene)]2 in acetonitrile
Ambient temperature;
参考文献
Soga, Tsunehiko; Takenoshita, Haruhiro; Yamada, Masaaki; Mukaiyama, Teruaki
Bulletin of the Chemical Society of Japan, 1990 , vol. 63, # 11 p. 3122 - 3131
反应条件
ethenetetracarbonitrile in acetonitrile
1 h; Heating;
参考文献
Miura, Tsuyoshi; Masaki, Yukio
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1995 , # 17 p. 2155 - 2158
反应条件
sodium hydroxide; tetrabutylammomium bromide in dichloromethane
4 h; Ambient temperature;
参考文献
Swamy, Vishwanath M.; Sarkar, Amitabha
Tetrahedron Letters, 1998 , vol. 39, # 10 p. 1261 - 1264
反应条件
indium(III) chloride in water
Ambient temperature;
参考文献
Loh, Teck-Peng; Liung, Sarah B. K. W.; Tan, Kee-Leng; Wei, Lin-Li
Tetrahedron, 2000 , vol. 56, # 20 p. 3227 - 3237
反应条件
lithium perchlorate; sodium carbonate in acetonitrile
Yields of byproduct given;
参考文献
Renaud, Roger N.; Stephens, Campbell J.; Brochu, Gaetan
Canadian Journal of Chemistry, 1984 , vol. 62, p. 565 - 569
