反应条件
in neat (no solvent, gas phase) byproducts: Na[C6F13BF3], Na[C7F15BF3], CO; a reactor charged with (CF3)3BCO at -196°C, warmed to room temp. and kept at this temp. for 20 h, cooled to -196°C, CO removed (vac.), the content transferred (vac.) to NaF and CH3CN at -196°C, stirred for 10 min at room temp.; filtered, evapd. (vac.); obtained as a mixt. of NaBF4, NaC2F5BF3, NaC3F7BF3, NaC4F9BF3, NaC5F11BF3, NaC6F13BF3, NaC7F15BF3.;
参考文献
Inorganic Chemistry, , vol. 43, # 2 p. 490 - 505
