2-[(dimethylamino)methyl]-1-thiophenolato-copper(I); caesium carbonate in 1-methyl-pyrrolidin-2-one T=160°C; 6 h; Inert atmosphere;

potassium phosphate; copper(l) iodide; 2,2,6,6-tetramethylheptane-3,5-dione; water in ethanol T=130°C; 30 h; Inert atmosphereSealed tube; chemoselective reaction;

palladium diacetate; 2-tBuP-3,4,5,6-Me4-2',4',6'-tri-isopropylbiphenyl; caesium carbonate in toluene T=90°C; 24 h;

aluminium bei der Destillation;

1-(2-di-tert-butylphosphino-3,4,5,6-tetramethylphenyl)-2-neopentylnaphthalene; palladium diacetate; caesium carbonate; tributyl-amine T=90°C; 24 h; Product distribution; Further Variations:Reagents;

1: ortho-cresol With tris-(dibenzylideneacetone)dipalladium(0); sodium hydroxide; di-tert-butyl(2′,4′,6′-triisopropylbiphenyl-2-yl)phosphine in 1,4-dioxane; polyethylene glycol; water T=80°C; 1 h; 2: 1-bromo-3,5-dimethyl-benzene in 1,4-dioxane; polyethylene glycol; water T=80°C;