1,2-二[2-甲基苯并[B]噻吩-3-基]-3,3,4,4,5,5-六氟-1-环戊烯合成路线 （共 5 条）
反应条件
1: 3-bromo-2-methylbenzolt;bgt;thiophene With n-butyllithium in tetrahydrofuran; hexane T=0°C; 2: 1,2,3,3,4,4,5,5-octafluorocyclopentene in tetrahydrofuran; hexane T=0°C; Further stages.;
参考文献
Ushiogi, Yousuke; Hase, Tomoyuki; Iinuma, Yoshiharu; Takata, Atsushi; Yoshida, Jun-Ichi
Chemical Communications, 2007 , # 28 p. 2947 - 2949
反应条件
1: 2-methyl-3-iodobenzothiophene With n-butyllithium in tetrahydrofuran; hexane T=-78°C; 1 h; Inert atmosphere; 2: 1,2,3,3,4,4,5,5-octafluorocyclopentene in tetrahydrofuran; hexane T=-78 - 20°C; 1 h; Inert atmosphere;
参考文献
Vazquez, Alvaro J.; Nudelman, Norma Sbarbati
Journal of Physical Organic Chemistry, 2012 , vol. 25, # 11 p. 925 - 932
反应条件
1: 3-bromo-2-methylbenzolt;bgt;thiophene With n-butyllithium in tetrahydrofuran; hexane T=-78°C; 1 h; 2: 1-(2-methylbenzo[b]thiophen-3-yl)-2,3,3,4,4,5,5-heptafluorocyclopentane in tetrahydrofuran; hexane T=-95 - 20°C;
参考文献
Yagi, Kyoko; Irie, Masahiro
Bulletin of the Chemical Society of Japan, 2003 , vol. 76, # 8 p. 1625 - 1628
反应条件
n-butyllithium in diethyl ether T=-78°C; Inert atmosphere;
参考文献
Edelsztein, Valeria C.; Jares-Erijman, Elizabeth A.; Spagnuolo, Carla C.; Di Chenna, Pablo H.; Muellen, Klaus
Journal of Materials Chemistry, 2012 , vol. 22, # 41 p. 21857 - 21861,5
反应条件
1.1: iodine; periodic acid; sulfuric acid / acetic acid; water / 3 h 2.1: n-butyllithium / hexane; tetrahydrofuran / 1 h / -78 °C / |Inert atmosphere 2.2: 1 h / -78 - 20 °C / |Inert atmosphere View Scheme
参考文献
Vazquez, Alvaro J.; Nudelman, Norma Sbarbati
Journal of Physical Organic Chemistry, 2012 , vol. 25, # 11 p. 925 - 932
