di-μ-chlorotetrakis(η2-methylenecyclopropane)dirhodium
T=25°C; 0.5 h; other hydrosilylating agents, var. amount of catalyst and time; Product distribution;
参考文献
Donskaya, N. A.; Yur'eva, N. M.; Voevodskaya, T. I.; Sigeev, A. S.; Beletskaya, I. P.
Russian Journal of Organic Chemistry, 1994 , vol. 30, # 6.1 p. 853 - 859
Zhurnal Organicheskoi Khimii, 1994 , vol. 30, # 6 p. 801 - 806
Whitmore, F. C.; Sommer, L. H.; Giorgio, P. A. di; Strong, W. A.; Strien, R. E. van; et al.
Journal of the American Chemical Society, 1946 , vol. 68, p. 475 - 481
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Gmelin Handbook: Si: MVol.C, 14, page 41 - 44
tert.-butylhydroperoxide; Wilkinson's catalyst in chlorobenzene
T=50°C; 1 h; further temperature and solvents, variation of ratio of the educts and amount of t-butyl hydroperoxide; addition of inhibitors; competition with isomerisation of hex-1-ene; Product distributionMechanism;
参考文献
Dickers, Hugh M.; Haszeldine, Robert N.; Malkin, Leslie S.; Mather, Adrian P.; Parish, R. V. (Dick)
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1980 , p. 308 - 313
Terent'ev, A. B.; Savos'kina, I. V.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1989 , vol. 38, # 2 p. 1970 - 1971
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1989 , vol. 9, p. 2140 - 2142
