(9CI)-(3,3-二氟-1-环丙烯-1-基)-苯合成路线 (共 6 条)
反应条件
potassium fluoride; 18-crown-6 ether; triphenylphosphine in ethylene glycol dimethyl ether T=25°C;
参考文献
Bessard, Yves; Schlosser, Manfred
Tetrahedron, 1991 , vol. 47, # 35 p. 7323 - 7328
反应条件
tetrabutylammomium bromide in toluene T=20 - 110°C; 2 h; Inert atmosphere; TimeTemperatureSolvent;
参考文献
Li, Lingchun; Wang, Fei; Ni, Chuanfa; Hu, Jinbo
Angewandte Chemie - International Edition, 2013 , vol. 52, # 47 p. 12390 - 12394
Angew. Chem., 2013 , vol. 125, # 47 p. 12616 - 12620,5
反应条件
NAF in diethylene glycol dimethyl ether 2 h; bath temperature 120 deg C;
参考文献
Xu, Wei; Chen, Qing-Yun
Journal of Organic Chemistry, 2002 , vol. 67, # 26 p. 9421 - 9427
反应条件
tetrabutyl-ammonium chloride in toluene T=110°C; [2+1] cycloaddition; 4 h;
参考文献
Wang, Fei; Zhang, Wei; Zhu, Jieming; Li, Huaifeng; Huang, Kuo-Wei; Hu, Jinbo
Chemical Communications, 2011 , vol. 47, # 8 p. 2411 - 2413
反应条件
tetrabutyl-ammonium chloride in toluene T=100°C; 4 h;
参考文献
Wang, Fei; Zhang, Wei; Zhu, Jieming; Li, Huaifeng; Huang, Kuo-Wei; Hu, Jinbo
Chemical Communications, 2011 , vol. 47, # 8 p. 2411 - 2413
反应条件
sodium iodide in tetrahydrofuran T=110°C; 2 h; Inert atmosphere;
参考文献
Wang, Fei; Luo, Tao; Hu, Jinbo; Wang, Ying; Krishnan, Hema S.; Jog, Parag V.; Ganesh, Somesh K.; Prakash, G. K. Surya; Olah, George A.
Angewandte Chemie - International Edition, 2011 , vol. 50, # 31 p. 7153 - 7157