in hexane
Irradiation (UV/VIS); addn. of rhenium compd. and iodine to degassed anhyd. hexane, purging with CO for 10 min, irradiation for 4 h with medium pressure Hg lamp; Schmidt S.P., Trogler W.C., Basolo F. In Inorganic syntheses; Angelici R.J.,Ed.; J. Wiley: New York, 1990; V. 28; evapn., dissolving in ethanol, addn. of aq. soln. of Na2S2O3, filtration, washing with water, drying;
参考文献
Cannizzo, Andrea; Blanco-Rodriguez, Ana Maria; Nahhas, Amal El; Sebera, Jakub; Zalis, Stanislav; Vlcek Jr., Antonin; Chergui, Majed
Journal of the American Chemical Society, 2008 , vol. 130, # 28 p. 8967 - 8974
acetonitrile in acetonitrile
Kinetics; byproducts: Re2(CO)9(MeCN); Irradiation (UV/VIS); Ar-atmosphere; Nd:Yag laser pulses (351 and 355 nm); not isolated, reaction followed by UV/VIS spectroscopy;
acetonitrile in acetonitrile
Kinetics; byproducts: Re2(CO)9(MeCN); Irradiation (UV/VIS); Ar-atmosphere; Nd:Yag laser pulses (351 and 355 nm); not isolated, reaction followed by UV/VIS spectroscopy;
acetonitrile in acetonitrile
Kinetics; byproducts: Re2(CO)9(MeCN); Irradiation (UV/VIS); Ar-atmosphere; Nd:Yag laser pulses (351 and 355 nm); not isolated, reaction followed by UV/VIS spectroscopy;
copper in neat (no solvent)
byproducts: CuI, KI; High Pressure; heating for 30 h K2(ReBr6) and Cu in rotary autoclave with CO at 200 atm to 200 °C;; extg. with petroleum ether;;
参考文献
Hieber, W.; Schulten, H.
Z. Anorg. Chem., 1940 , vol. 243, p. 167 - 167
Full Text Show Details
Hieber, W.; Schulten, H.
Z. Anorg. Chem., 1940 , vol. 243, p. 172 - 172
Full Text Show Details
Gmelin Handbook: Re: MVol., 35, page 121 - 123
in tetrahydrofuran
Rhenium-complex is suspended in THF under N2, addn. of KI, reaction mixture is stirred for 15 h at room temp.; light yellow soln. and a colourless ppt. are obtained, sepn. of ppt. and drying, removal of solvent of yellow soln., addn. of petrolether to resulting ppt., pptn. of (OC)5ReI, drying under vac., sublimation at 60°C, elem. anal.;
参考文献
Steil, Peter; Beck, Wolfgang; Stone, F. Gordon A.
Journal of Organometallic Chemistry, 1989 , vol. 368, p. 77 - 82
in hexane
byproducts: HI; hexane soln. of (C5Me4CH2CHCH2)Re(CO)2(I)(H) (0.199 mmol) bubbled with CO for 3 min, heated at 40°C for 3 h; chromy. (alumina), eluted (hexane), crystd. (hexane); elem. anal.;
参考文献
Godoy, Fernando; Gomez, Alejandra; Cardenas-Jiron, Gloria; Hugo Klahn; Lahoz, Fernando J.
Journal of Organometallic Chemistry, 2010 , vol. 695, # 3 p. 346 - 351
