Cl2 in neat (no solvent) reaction with slight detonation on heating of Si2F6 and Cl2;;
参考文献
Schumb, W. C.; Gamble, E. L.
Journal of the American Chemical Society, 1931 , vol. 53, p. 3191 - 3199
Full Text View citing articles Show Details
Gmelin Handbook: Si: MVol.B, 232, page 633 - 635
in neat (no solvent) reaction with detonation by strong heating of the mixt. for a short time;; isolation by fractional distillation;;
参考文献
Schumb, W. C.; Gamble, E. L.
Journal of the American Chemical Society, 1932 , vol. 54, p. 3943 - 3949
Full Text View citing articles Show Details
Gmelin Handbook: Si: MVol.B, 262, page 708 - 710
in gas Kinetics; byproducts: SiF3I; gas phase pyrolysis at 603-652 K (various conditions, addn. of Ar or SiF4); monitored by spectrophotometry, product identification by IR and mass spectroscopy;
参考文献
Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics, , vol. 82, p. 837 - 848
in neat (no solvent) Si2F6 condensed onto SO3 at liq. N2 temp., allowed to attain room temp., heated to 400°C for 12 h; gaseous products analyzed by IR;
参考文献
Bulletin of the Chemical Society of Japan, , vol. 58, # 6 p. 1867 - 1868
in gas Kinetics; byproducts: SiF3I; gas phase pyrolysis at 603-652 K (various conditions, addn. of Ar or SiF4); monitored by spectrophotometry, product identification by IR and mass spectroscopy;
参考文献
Bains, Swroop K.; Noble, Paul N.; Walsh, Robin
Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics, 1986 , vol. 82, p. 837 - 848
