N-(4-溴苯基)-N-苯基-1-萘胺合成路线 （共 7 条）
反应条件
tri-tert-butyl phosphine; sodium t-butanolate; tris-(dibenzylideneacetone)dipalladium(0) in toluene 12 h; Heating;
参考文献
DOOSAN CORPORATION
Patent: WO2009/82157 A2, 2009 ;
Location in patent: Page/Page column 27 ;
反应条件
sodium t-butanolate; bis-triphenylphosphine-palladium(II) chloride in xylene T=130°C; 12 h;
参考文献
EP1559706 A1, ;
Page/Page column 38 ;
反应条件
1,1'-bis(diphenylphosphino)ferrocene; palladium diacetate; sodium t-butanolate in toluene T=90°C; Buchwald-Hartwig coupling; 15 h; Inert atmosphere;
参考文献
Chang, Yuan Jay; Chow, Tahsin J.
Tetrahedron, 2009 , vol. 65, # 24 p. 4726 - 4734
反应条件
1: With n-butyllithium in tetrahydrofuran
T=-78°C;
2: With boric acid trimethyl ester in tetrahydrofuran
T=-78 - 20°C;
3: With hydrogenchloride in tetrahydrofuran; water
参考文献
DOOSAN CORPORATION
Patent: WO2009/82157 A2, 2009 ;
Location in patent: Page/Page column 27-28 ;
反应条件
1: N-(4-bromophenyl)-N-phenylnaphthalen-1-amine With n-butyllithium in tetrahydrofuran; hexane
T=-78°C; 1 h;
2: tri-isopropoxy-borane in tetrahydrofuran; hexane
T=-78 - 20°C;
参考文献
Jia, Wen Li; Moran, Mark J.; Yuan, Yan-Yan; Lu, Zheng Hong; Wang, Suning
Journal of Materials Chemistry, 2005 , vol. 15, # 32 p. 3326 - 3333
反应条件
sodium t-butanolate; tri-tert-butyl phosphine; bis(dibenzylideneacetone)-palladium(0) in toluene
2 h; Heating / reflux;
参考文献
Jeon, Byung-Sun; Cho, Wook-Dong; Kim, Jeung-Gon; Jeon, Sang-Young; Kim, Yeon-Hwan
Patent: US2010/65828 A1, 2010 ;
Location in patent: Page/Page column 120 ;
