反应条件
1: N-methylmorpholine N-oxide; OsO4; H2O / acetone / 24 h / 20 °C
2: 20.16 g / p-TSA / acetone / 20 h / 20 °C
3: 93 percent / KCN / methanol / 2 h / 20 °C
4: 76 percent / pyridinium chlorochromate; Celite / CH2Cl2 / 15 h / 20 °C
5: 84 percent / sodium borohydride; CeCl3*7H2O / methanol / 0.75 h / 0 °C
6: 72 percent / imidazole / dimethylformamide / 12 h / 20 °C
7: KOH; KMnO4; MgSO4 / methanol; H2O / 2 h / 0 °C
8: 710 mg / sodium borohydride / propan-2-ol / 1 h / 0 °C
9: 85 percent / pyridine / CH2Cl2 / 0 - 20 °C
10: 88 percent / tetrabutylammonium fluoride / tetrahydrofuran / 2 h / 20 °C
11: diisopropyl azodicarboxylate; triphenylphosphine / tetrahydrofuran / 18 h / 55 °C
12: 980 mg / NH3 / methanol / 48 h / 110 °C
13: 84 percent / trifluoroacetic acid; H2O / 2 h / 20 °C
View Scheme
参考文献
Rajappan, Vasathakumar P; Yin, Xueqiang; Schneller, Stewart W
Tetrahedron, 2002 , vol. 58, # 49 p. 9889 - 9895
