oxygen in neat (no solvent)
Kinetics; byproducts: O, Cl; fast-flow reactor, Ar flow gas, 7.5-31-2 Torr, 540-1670 K; measurement of relative concn. by laser-induced fluorescence (272.0 nm);
参考文献
Slavejkov, Aleksandar G.; Rogowski, Donald F.; Fontijn, Arthur
Chemical Physics Letters, 1988 , vol. 143, p. 26 - 30
in gaseous matrix
BO2 radicals produced by the reaction of BCl3 with O atoms (in presence of excess O2) formed on microwave discharge of a O2/He mixture;
参考文献
Maki, Arthur G.; Burkholder, James B.; Sinha, Amitabha; Howard, Carleton J.
Journal of Molecular Spectroscopy, 1988 , vol. 130, p. 238 - 248
in solid matrix
Ar-matrix (Xe-, or Kr- matrices were also used); boron vapour and a large excess of the matrix gas containing 2percent oxygen were cocondensed on a window cooled to 10 K; the deposition time varied from 2 to 5 h;; no product isolation;;
参考文献
Boucher, Ray; Wang, Yi; Klabunde, Kenneth J.
High Temperature Science, 1991 , vol. 31, p. 87 - 104
in gas
byproducts: B2O3; react. of BCl3 in flowing of O + O2 (excess of O atoms formed by discharge through O2 or O2 + Ar mixts. at 1 Torr); not isolated; detn. by chemoluminescence;
参考文献
Hodgson, Andrew
Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics, 1985 , vol. 81, p. 1445 - 1462
→
反应条件
in gas
high temp. react. with silica gel melt at 2500 K, equil. pressure of gaseous reagents: 2.89E-2 atm;
参考文献
Agayan, G. S.; Yudin, B. F.; Ordan'yan, S. S.
Journal of Applied Chemistry USSR (English Translation), 1988 , vol. 61, p. 2039 - 2042
Zhurnal Prikladnoi Khimii (Sankt-Peterburg, Russian Federation), 1988 , vol. 61, p. 2229 - 2231
→
反应条件
in gas
high temp. react. with silica gel melt at 2500 K, equil. pressure of gaseous reagents: 3.60E-2 atm;
参考文献
Agayan, G. S.; Yudin, B. F.; Ordan'yan, S. S.
Journal of Applied Chemistry USSR (English Translation), 1988 , vol. 61, p. 2039 - 2042
Zhurnal Prikladnoi Khimii (Sankt-Peterburg, Russian Federation), 1988 , vol. 61, p. 2229 - 2231
