反应条件
in tetrahydrofuran under N2; soln. of 5 mmol NaMn(CO)5 in THF cooled to -78°C, 5.25 mmol (C6H4O2)CHCOCl added; mixt. warmed up to room temp. and stirred overnight; pptd. NaCl filtered off, solvent removed; residue extd. with petroleum ether; chromy. (silica gel, petroleum ether/ether (10:1)); pentane soln. cooled, recrystn. from petroleum ether at -80°C; elem anal.;
参考文献
Loewe, Christiane; Huttner, Gottfried; Zsolnai, Laszlo; Berke, Heinz
Zeitschrift fuer Naturforschung, B: Chemical Sciences, 1988 , vol. 43, # 1 p. 25 - 30
