(4-二苯甲基苯基)-二甲胺合成路线 （共 22 条）
反应条件
bis(η3-allyl-μ-chloropalladium(II)); sodium hydroxide; SIDip*HCl in 1,4-dioxane; water T=120°C; 12 h; Inert atmosphere;
参考文献
Nambo, Masakazu; Crudden, Cathleen M.
Angewandte Chemie - International Edition, 2014 , vol. 53, # 3 p. 742 - 746
Angew. Chem., 2014 , vol. 126, # 3 p. 761 - 765,5
反应条件
hydrazine hydrate; palladium on activated charcoal in ethanol Reduction; 1 h; Heating;
参考文献
Cho, Bongsup P; Blankenship, Lonnie R; Moody, Joanna D; Doerge, Daniel R; Beland, Frederick A; Culp, Sandra J
Tetrahedron, 2000 , vol. 56, # 38 p. 7379 - 7388
反应条件
1.1: BuLi / hexane; tetrahydrofuran / 4 h / -78 - 20 °C 1.2: HCl / methanol / 1 h / Heating 2.1: NH2NH2*H2O / 10 percent Pd/C / ethanol / 1 h / Heating View Scheme
参考文献
Cho, Bongsup P; Blankenship, Lonnie R; Moody, Joanna D; Doerge, Daniel R; Beland, Frederick A; Culp, Sandra J
Tetrahedron, 2000 , vol. 56, # 38 p. 7379 - 7388
反应条件
1.1: BuLi / hexane; tetrahydrofuran / 4 h / -78 - 20 °C 1.2: HCl / methanol / 1 h / Heating 2.1: NH2NH2*H2O / 10 percent Pd/C / ethanol / 1 h / Heating View Scheme
参考文献
Cho, Bongsup P; Blankenship, Lonnie R; Moody, Joanna D; Doerge, Daniel R; Beland, Frederick A; Culp, Sandra J
Tetrahedron, 2000 , vol. 56, # 38 p. 7379 - 7388
反应条件
1.1: cyclohexane; diethyl ether / -78 - 20 °C 1.2: HCl / methanol / Heating 2.1: NH2NH2*H2O / 10 percent Pd/C / ethanol / 1 h / Heating View Scheme
参考文献
Cho, Bongsup P; Blankenship, Lonnie R; Moody, Joanna D; Doerge, Daniel R; Beland, Frederick A; Culp, Sandra J
Tetrahedron, 2000 , vol. 56, # 38 p. 7379 - 7388
反应条件
1.1: cyclohexane; diethyl ether / -78 - 20 °C 1.2: HCl / methanol / Heating 2.1: NH2NH2*H2O / 10 percent Pd/C / ethanol / 1 h / Heating View Scheme
参考文献
Cho, Bongsup P; Blankenship, Lonnie R; Moody, Joanna D; Doerge, Daniel R; Beland, Frederick A; Culp, Sandra J
Tetrahedron, 2000 , vol. 56, # 38 p. 7379 - 7388
反应条件
KN(SiMe3)2; palladium diacetate; Nixantphos in CPME T=24°C; 12 h; Inert atmosphere;
参考文献
Bellomo, Ana; Zhang, Jiadi; Trongsiriwat, Nisalak; Walsh, Patrick J.
Chemical Science, 2013 , vol. 4, # 2 p. 849 - 857
反应条件
in acetonitrile T=20°C; desilylation; Flash photolysis;
参考文献
Tasis, Dimitrios A.; Siskos, Michael G.; Zarkadis, Antonios K.; Steenken, Steen; Pistolis, Georgios
Journal of Organic Chemistry, 2000 , vol. 65, # 14 p. 4274 - 4280
反应条件
1: 2-dicyclohexylphosphino-1,1'-biphenyl; palladium diacetate; lithium tert-butylate / 1,4-dioxane / 12 h / 120 °C / |Inert atmosphere 2: SIDip*HCl; sodium hydroxide; bis(η3-allyl-μ-chloropalladium(II)) / 1,4-dioxane; water / 12 h / 120 °C / |Inert atmosphere View Scheme
参考文献
Nambo, Masakazu; Crudden, Cathleen M.
Angewandte Chemie - International Edition, 2014 , vol. 53, # 3 p. 742 - 746
Angew. Chem., 2014 , vol. 126, # 3 p. 761 - 765,5
反应条件
zinc(II) chloride T=180 - 190°C;
参考文献
Doebner; Petschow
Justus Liebigs Annalen der Chemie, 1887 , vol. 242, p. 341
