(E)-己-3-烯酸甲酯合成路线 （共 11 条）
参考文献
Curtis, Neil R.; Holmes, Andrew B.; Looney, Mark G.
Tetrahedron, 1991 , vol. 47, # 34 p. 7171 - 7178
反应条件
cesium fluoride in N,N-dimethyl-formamide
T=10 - 15°C; 24 h;
参考文献
Sato, Tsuneo; Otera, Junzo; Nozaki, Hitosi
Journal of Organic Chemistry, 1992 , vol. 57, # 7 p. 2166 - 2169
反应条件
polyethylene glycol; sodium tetrahydroborate; palladium dichloride in dichloromethane
T=10°C; P=735.5 Torr; 1 h; further solvent: EtOH; further catalyst: Pd/C; Product distribution;
参考文献
Suzuki, Nobutaka; Tsukanaka, Tsuneaki; Nomoto, Tateo; Ayaguchi, Yasuo; Izawa, Yasuji
Journal of the Chemical Society, Chemical Communications, 1983 , # 9 p. 515 - 516
反应条件
N,N,N',N',N'',N''-hexamethylphosphoric triamide; methyl cuprate; diisobutylaluminium hydride in tetrahydrofuran; hexane
T=-50°C; 1.5 h; other unsaturated conjugated carbonyl compounds; other reaction partners; var. time and temps.; comparisons with the reactions without cuprous compds.; Product distribution;
参考文献
Tsuda, Tetsuo; Hayashi, Toshio; Satomi, Hiroshi; Kawamoto, Tadashi; Saegusa, Takeo
Journal of Organic Chemistry, 1986 , vol. 51, # 4 p. 537 - 540
反应条件
sodium tetrahydroborate; palladium on activated charcoal in ethanol
T=10°C; 2.25 h; Yield given. Yields of byproduct given;
参考文献
Suzuki, N.; Kaneko, Y.; Tsukanaka, T.; Nomoto, T.; Ayaguchi, Y.; Izawa, Y.
Tetrahedron, 1985 , vol. 41, # 12 p. 2387 - 2392
参考文献
Ansell,M.F. et al.
Journal of the Chemical Society [Section] C: Organic, 1968 , p. 217 - 225
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Sato, Tsuneo; Otera, Junzo; Nozaki, Hitosi
Journal of Organic Chemistry, 1992 , vol. 57, # 7 p. 2166 - 2169
反应条件
1: Na, liq. NH3
View Scheme
参考文献
Ansell,M.F. et al.
Journal of the Chemical Society [Section] C: Organic, 1968 , p. 217 - 225
反应条件
hydrogenchloride
1.) 3 d, 35 deg C, THF; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Hoberg, Heinz; Jenni, Klaus
Journal of Organometallic Chemistry, 1987 , vol. 322, p. 193 - 202
反应条件
methanol; sulfuric acid; ammonia; lithium
1) -78 degC, 60 min, 2) room temp., 24 h; other amount of Li: 10 eq.; Product distributionMechanism;
参考文献
Blenderman, Walter G.; Joullie, Madeleine M.; Preti, George
Journal of Organic Chemistry, 1983 , vol. 48, # 19 p. 3206 - 3213
反应条件
oxygen; oxygen; copper(l) chloride; palladium dichloride in 1,4-dioxane; water
T=50°C; 12 h;
参考文献
Nagashima, Hideo; Sakai, Kiyomi; Tsuji, Jiro
Chemistry Letters, 1982 , p. 859 - 860
