甲基(3Z)-3-己烯酸酯合成路线 （共 14 条）
反应条件
methanol; sulfuric acid; ammonia; lithium 1) -78 degC, 60 min, 2) room temp., 24 h; other amount of Li: 10 eq.; Product distributionMechanism;
参考文献
Blenderman, Walter G.; Joullie, Madeleine M.; Preti, George
Journal of Organic Chemistry, 1983 , vol. 48, # 19 p. 3206 - 3213
反应条件
sodium hydroxide; sodium tetrahydroborate; zinc 2-ethylhexanoate 1.) THF, 70 deg C, 4 h, 2.) 40 deg, 1 h; Yield givenMultistep reaction;
参考文献
Mimoun
Journal of Organic Chemistry, 1999 , vol. 64, # 7 p. 2582 - 2589
反应条件
1: 1.95 g / m-CPBA / CH2Cl2 / 0 - 5 °C
2: NaN3, LiClO4 / acetonitrile / 18 h / 80 °C
View Scheme
参考文献
Azzena, Francesca; Crotti, Paolo; Favero, Lucilla; Pineschi, Mauro
Tetrahedron, 1995 , vol. 51, # 48 p. 13409 - 13422
反应条件
oxygen O2, singlet
2.) reduction; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Stratakis, Manolis; Orfanopoulos, Michael
Tetrahedron Letters, 1997 , vol. 38, # 6 p. 1067 - 1070
