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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
139109-02-7
合成路线
（共 5 条）
58479-61-1
叔丁基二苯基氯硅烷
→
反应条件
139109-02-7
反应条件
1: 100 percent / imidazole / dimethylformamide / 1 h / 20 °C 2: 70 percent / MCPBA / CHCl3 / 1 h / 0 °C 3: HIO4*2H2O / tetrahydrofuran; diethyl ether / 1 h / 0 °C View Scheme
参考文献
Muto, Shin-Etsu; Nishimura, Yutaka; Mori, Kenji
European Journal of Organic Chemistry, 1999 , # 9 p. 2159 - 2165
106-24-1
香叶醇
→
反应条件
139109-02-7
反应条件
1: 100 percent / imidazole / dimethylformamide / 1 h / 20 °C 2: 70 percent / MCPBA / CHCl3 / 1 h / 0 °C 3: HIO4*2H2O / tetrahydrofuran; diethyl ether / 1 h / 0 °C View Scheme
参考文献
Jenn, Thierry; Heissler, Denis
Tetrahedron, 1998 , vol. 54, # 1-2 p. 107 - 118
40036-54-2
→
反应条件
139109-02-7
反应条件
1: 98 percent / imidazole / dimethylformamide / 2.5 h / Ambient temperature 2: 73 percent / HIO4*H2O / diethyl ether; tetrahydrofuran / 1 h / 0 °C View Scheme
参考文献
Zoretic, Phillip A.; Zhang, Yongzheng; Fang, Haiquan; Ribeiro, Anthony A.; Dubay, George
Journal of Organic Chemistry, 1998 , vol. 63, # 4 p. 1162 - 1167
139109-02-7
→
反应条件
130595-24-3
Phomactin A
反应条件
1.1: zinc; triphenylphosphine / CH2Cl2 / 1 h / 0 °C 1.2: CH2Cl2 / 5 h / 20 °C 2.1: n-butyllithium / diethyl ether; hexane / 1 h / 0 °C 3.1: n-butyllithium / tetrahydrofuran; hexane / 0.5 h / -78 °C 3.2: 816 mg / tetrahydrofuran; hexane / 3 h / 20 °C 4.1: TBAF / tetrahydrofuran / 1 h / 20 °C 5.1: 10.5 g / imidazole / dimethylformamide / 12 h / 20 °C 6.1: bis(cyclopentadienyl)zirconium chloride hydride / benzene / 12 h / 40 °C 6.2: 65 percent / iodine / benzene / 0.08 h / 20 °C 7.1: 92 percent / TBAF / tetrahydrofuran / 0.5 h / 20 °C 8.1: isopropyl D-tartrate; titanium isopropoxide; tert-butylhydroperoxide / CH2Cl2 / 2 h / -20 °C 9.1: 82 percent / triethylamine; sulfur trioxide pyridine complex / CH2Cl2; dimethylsulfoxide / 1 h / 0 °C 10.1: t-butyllithium / diethyl ether; pentane / 0.5 h / -78 °C 10.2: 51 percent / TMEDA / diethyl ether; pentane / 0.08 h / -78 °C 11.1: 90 percent / Dess-Martin periodinane; sodium bicarbonate / CH2Cl2 / 1 h / 20 °C 12.1: TBAF / tetrahydrofuran / 0.5 h / 0 °C 13.1: 25 mg / HCl / 2-methyl-butan-2-ol / 2 h / 20 °C 14.1: 83 percent / imidazole / dimethylformamide / 2 h / 20 °C 15.1: 87 percent / DDQ / CH2Cl2; H2O / 0.5 h / 20 °C 16.1: 81 percent / pyridine / CH2Cl2 / 0.17 h / -78 °C 17.1: 9-BBN / tetrahydrofuran / 2 h / 40 °C 17.2: 37 percent / thallium carbonate; triphenylarsine / [1,1'-bis(diphenylphosphino)ferrocene]dichloropalladium(II) / tetrahydrofuran; dimethylformamide; H2O / 12 h / 20 °C 18.1: 78 percent / TBAF / tetrahydrofuran / 0.5 h / 0 °C View Scheme
参考文献
Mohr, Peter J.; Halcomb, Randall L.
Journal of the American Chemical Society, 2003 , vol. 125, # 7 p. 1712 - 1713
139109-02-7
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反应条件
55546-66-2
反应条件
1: 80 percent / KHMDS, 18-crown-6 / tetrahydrofuran / -78 °C 2: 95 percent / DIBALH / tetrahydrofuran / -40 - 0 °C 3: 95 percent / NCS, DMS / CH2Cl2 / -40 - 0 °C 4: tetrahydrofuran / -78 °C 5: 82 percent / TBAF / tetrahydrofuran / 1.) 0 deg C, 1 h, 2.) room temperature, 3 h View Scheme
参考文献
Sen, Stephanie E.; Ewing, Gregory J.
Journal of Organic Chemistry, 1997 , vol. 62, # 11 p. 3529 - 3536
