4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-十七氟十一胺合成路线 （共 8 条）
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139175-50-14,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-十七氟十一胺
反应条件
ammonia; hydrogen; nickel monoaluminide in ethanol
参考文献
Atochem
Patent: US4832859 A1, 1989 ;
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139175-50-14,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-十七氟十一胺
反应条件
hydrogen; palladium on activated charcoal in ethanol; hexane Hydrogenolysis;
参考文献
Rocaboy, Christian; Bauer, Walter; Gladysz, John A.
European Journal of Organic Chemistry, 2000 , # 14 p. 2621 - 2628
200112-75-04,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-十七氟十一烷基碘
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139175-50-14,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-十七氟十一胺
反应条件
ammonia in tetrahydrofuran T=25°C; 24 h;
参考文献
Szlavik, Zoltan; Tarkanyi, Gabor; Goemoery, Agnes; Tarczay, Gyoergy; Rabai, Jozsef
Journal of Fluorine Chemistry, 2001 , vol. 108, # 1 p. 7 - 14
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139175-50-14,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-十七氟十一胺
反应条件
1: With hydrazine hydrate in methanol 1 h; Heating; 2: With hydrogenchloride in methanol 1 h; 32;
参考文献
Abulikemu, Abudurexiti; Halasz, Gabor; Csampai, Antal; Goemoery, Agnes; Rabai, Jozsef
Journal of Fluorine Chemistry, 2004 , vol. 125, # 7 p. 1143 - 1146
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139175-50-14,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-十七氟十一胺
反应条件
1: 96 percent / Dess-Martin periodinane / CH2Cl2 / 2 h 2: 90 percent / Na(AcO)3BH / tetrahydrofuran / 5 h 3: 98 percent / H2 / 10 percent Pd/C / ethanol; hexane View Scheme
参考文献
Rocaboy, Christian; Bauer, Walter; Gladysz, John A.
European Journal of Organic Chemistry, 2000 , # 14 p. 2621 - 2628
→
139175-50-14,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-十七氟十一胺
反应条件
1: 90 percent / Na(AcO)3BH / tetrahydrofuran / 5 h 2: 98 percent / H2 / 10 percent Pd/C / ethanol; hexane View Scheme
参考文献
Rocaboy, Christian; Bauer, Walter; Gladysz, John A.
European Journal of Organic Chemistry, 2000 , # 14 p. 2621 - 2628
→
139175-50-14,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-十七氟十一胺
反应条件
1.1: 84 percent / Et3N; H2 / Pd/C / tetrahydrofuran / 20 °C / 2068.59 - 2585.74 Torr 2.1: hydrazine hydrate / methanol / 1 h / Heating 2.2: 77 percent / aq. HCl / methanol / 1 h / 32 View Scheme
参考文献
Abulikemu, Abudurexiti; Halasz, Gabor; Csampai, Antal; Goemoery, Agnes; Rabai, Jozsef
Journal of Fluorine Chemistry, 2004 , vol. 125, # 7 p. 1143 - 1146
200112-75-04,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-十七氟十一烷基碘
→
139175-50-14,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-十七氟十一胺
反应条件
1.1: 80 percent / dimethylformamide / 7 h / 100 °C 2.1: hydrazine hydrate / methanol / 1 h / Heating 2.2: 77 percent / aq. HCl / methanol / 1 h / 32 View Scheme
参考文献
Abulikemu, Abudurexiti; Halasz, Gabor; Csampai, Antal; Goemoery, Agnes; Rabai, Jozsef
Journal of Fluorine Chemistry, 2004 , vol. 125, # 7 p. 1143 - 1146
