(3Z)-6'-甲氧基-3,5'-二去氢-5',11-二氢脱氧辛可宁-9-基乙酸酯合成路线 （共 4 条）
反应条件
pyridine T=25°C; 16 h;
参考文献
Carroll, F. Ivy; Abraham, Philip; Gaetano, Kevan; Mascarella, S. Wayne; Wohl, Ronald A.; et al.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1991 , # 12 p. 3017 - 3026
反应条件
1: 48percent aq. hydrobromic acid, HBr(g) / a.) 0 deg C, 1 h, b.) 25 deg C, 1 h 2: 79 percent / DBU / dimethylsulfoxide / 2 h / 85 - 90 °C 3: 82 percent / pyridine / 16 h / 25 °C View Scheme
参考文献
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), , # 12 p. 3017 - 3026
反应条件
1: 79 percent / DBU / dimethylsulfoxide / 2 h / 85 - 90 °C 2: 82 percent / pyridine / 16 h / 25 °C View Scheme
参考文献
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), , # 12 p. 3017 - 3026
反应条件
sodium periodate; osmium(VIII) oxide 1.) 80percent HOAc, 25 deg C, 3 h, 2.) 4 deg C, 16 h; Yield given. Multistep reaction;
参考文献
Carroll, F. Ivy; Abraham, Philip; Gaetano, Kevan; Mascarella, S. Wayne; Wohl, Ronald A.; et al.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1991 , # 12 p. 3017 - 3026
