反式-双(三苯基膦)合氯化羰基铑(Ⅰ)合成路线 （共 95 条）
反应条件
water in N,N-dimethyl-formamide reagents mixed in DMF in a closed Schlenk tube without any reflux, heated under reflux, after 15 min cooled to room temp., 1.95 equiv. phosphaneadded; cold water added, filtered, washed with water, elem. anal.;
参考文献
Serp, Philippe; Hernandez, Marc; Richard, Brigitte; Kalck, Philippe
European Journal of Inorganic Chemistry, 2001 , # 9 p. 2327 - 2336
反应条件
in acetonitrile evacuated and N2 added two times; acetonitrile-acid chloride introduced; evacuated until the solvent boiled at room temp. then N2 added rapidly; cycles repeated; cooled to -75°C; sealed; in oil bath 85°C 24 h; decane added; styrene distd.; Rh comp. recrystd. from CH2Cl2; from filtrate chromd. styryl(PPh3)Cl;
参考文献
Journal of the American Chemical Society, , vol. 103, # 6 p. 1478 - 1485
反应条件
carbon monoxide in benzene Kinetics; react. of metal complex with CO in deaerated C6H6 under Ar; not isolated, detd. spect.;
参考文献
Journal of the American Chemical Society, , vol. 109, # 2 p. 436 - 442
反应条件
carbon monoxide in benzene Kinetics; react. of Rh-complex with CO in C6H6 at 25.0°C (stopped-flow react., exclusion of air); not isolated, detd. spect.;
参考文献
Journal of the American Chemical Society, , vol. 109, # 2 p. 436 - 442
反应条件
carbon monoxide in benzene Kinetics; react. of metal complex with CO in deaerated C6H6 under Ar; not isolated, detd. spect.;
参考文献
Journal of the American Chemical Society, , vol. 109, # 2 p. 436 - 442
反应条件
[(2,2'-bipyridine)Ni(1,5-cyclooctadiene)] in tetrahydrofuran byproducts: L-leucine oligomers; 16 h stirring; centrifuged, hexane was added, extd. with THF, layered with hexane;
参考文献
Journal of the American Chemical Society, , vol. 122, # 24 p. 5710 - 5717
反应条件
carbon monoxide in tetrahydrofuran a suspn. of Rh dimer in THF and CF3CCl3 were stirred at room temp. for 16 h under CO atmosphere; chlomy. over Florisil, eluent CHCl3;
参考文献
Booth, Brian L.; Casey, Geoffrey C.; Haszeldine, Robert N.
Journal of Organometallic Chemistry, 1982 , vol. 224, # 2 p. 197 - 205
反应条件
in further solvent(s) argon-filled glovebox, durene, bibenzyl, heating 24h at 70°C; detn. of products by GC;
参考文献
Andrews, Mark A.
Organometallics, 1989 , vol. 8, p. 2703 - 2708
反应条件
carbon monoxide in further solvent(s) 80-111°C (in boiling benzene, dichloroethane or toluene) in presence of air or N2; sepn. by chromy. on silica gel;
参考文献
Journal of the American Chemical Society, , vol. 103, p. 1847 - 1849
反应条件
in further solvent(s) argon-filled glovebox, heating 7.5h at 130°C, cooling to room temp.; gas phase was sampled and analyzed by GC and GC-MS, liquid phase was analyzed by IR;
参考文献
Organometallics, , vol. 8, p. 2703 - 2708
