反式-双(三苯基膦)合氯化羰基铑(Ⅰ)合成路线 （共 95 条）
反应条件
triphenylphosphine in toluene byproducts: carbon monoxyde; 2 equivalents of PPh3 at 25°C; NMR;
参考文献
Journal of Organometallic Chemistry, , vol. 450, # 1.2 p. 245 - 252
反应条件
carbon oxide sulfide in methanol; dichloromethane addn. of COS-satd. MeOH to soln. of Rh-complex in CH2Cl2, refluxing (3 h, pptn.); filtration, washing (alcohol, ether), drying (vac.); elem. anal.;
参考文献
Inorganica Chimica Acta, , vol. 40, p. 65 - 70
反应条件
in benzene Rh-complex was added to a soln. of Cl3CCOOH in benzene (1:1 ratio), mixt. was stirred at ambient temp. for 3 h under N2; evapd. to dryness under reduced pressure, triturated with Et2O;
参考文献
Boyar, Esther B.; Robinson, Stephen D.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1985 , p. 2113 - 2120
反应条件
styrene; hydrogen in methanol complex and ligand in soln. stirred under H2 for 30 min at 30-50°C, olefin added; evapd. (vac.), not isolated, detected by IR;
参考文献
Journal of Organometallic Chemistry, , vol. 192, # 2 p. 253 - 256
反应条件
carbon monoxide; SnCl2; PPh3 in methanol; dichloromethane CO at atmosphere pressure was bubbled for 5 min through a CH2Cl2/MeOH soln. of Rh-complex, phosphine and SnCl2; product was obtained in low yield; CH2Cl2 was evapd., ppt. was collected;
参考文献
Journal of Organometallic Chemistry, , vol. 322, p. 249 - 256
反应条件
in benzene dissoln. at room temp.; pptn. after several h;
参考文献
Iretskii, A. V.; Danilina, L. I.; Zhidkova, O. B.; Kukushkin, Yu. N.
Sov. J. Coord. Chem. (Engl. Transl.), 1990 , vol. 16, p. 521 - 524
Koordinatsionnaya Khimiya, 1990 , vol. 16, p. 971 - 974
反应条件
triphenylphosphine in dichloromethane byproducts: CO; N2-atmosphere; molar ratio Rh:PPh3=1:1.5, addn. of PPh3 to Rh-complex, stirring (15 min); solvent removal (reduced pressure), washing (hexane), drying (vac., roomtemp.);
参考文献
Inorganica Chimica Acta, , vol. 51, p. 253 - 262
反应条件
triphenylphosphine in dichloromethane byproducts: CO; N2-atmosphere; molar ratio Rh:PPh3=1:1.5, addn. of PPh3 to Rh-complex, stirring (15 min); solvent removal (reduced pressure), washing (hexane), drying (vac., roomtemp.);
参考文献
Inorganica Chimica Acta, , vol. 51, p. 253 - 262
反应条件
triphenylphosphine in dichloromethane byproducts: CO; N2-atmosphere; molar ratio Rh:PPh3=1:1.5, addn. of PPh3 to Rh-complex, stirring (15 min); solvent removal (reduced pressure), washing (hexane), drying (vac., roomtemp.);
参考文献
Inorganica Chimica Acta, , vol. 51, p. 253 - 262
反应条件
triphenylphosphine in dichloromethane byproducts: CO; N2-atmosphere; molar ratio Rh:PPh3=1:1.5, addn. of PPh3 to Rh-complex, stirring (15 min); solvent removal (reduced pressure), washing (hexane), drying (vac., roomtemp.);
参考文献
Inorganica Chimica Acta, , vol. 51, p. 253 - 262
