反式-双(三苯基膦)合氯化羰基铑(Ⅰ)合成路线 （共 95 条）
反应条件
triphenylphosphine in dichloromethane byproducts: CO; N2-atmosphere; molar ratio Rh:PPh3=1:1.5, addn. of PPh3 to Rh-complex, stirring (15 min); solvent removal (reduced pressure), washing (hexane), drying (vac., roomtemp.);
参考文献
Inorganica Chimica Acta, , vol. 51, p. 253 - 262
反应条件
HCl in not given N2-atmosphere;
参考文献
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), , p. 50 - 53
反应条件
in tetrahydrofuran a suspn. of Rh complex and 9,9-dichlorofluorene in THF in 1:1 mole ratiowas heated at 55°C for 3.5 h under N2; solvent was removed, residue extd. with light petroleum, bisfluorenylidene was isolated from the ext., extraction residue was RhCl(CO)(PPh3)2;
参考文献
Journal of Organometallic Chemistry, , vol. 224, # 2 p. 197 - 205
反应条件
HCl in not given N2-atmosphere;
参考文献
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), , p. 50 - 53
反应条件
HCl in not given N2-atmosphere;
参考文献
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), , p. 50 - 53
反应条件
1: not given 2: HCl / not given View Scheme
参考文献
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), , p. 50 - 53
反应条件
in tetrahydrofuran a mixt. of Ph2CCl2 and Rh-complex in THF in the presence of excess Ph2C=CH2 was heated at 50-60°C under N2; solvent was removed, residue chromd. over Al2O3;
参考文献
Journal of Organometallic Chemistry, , vol. 224, # 2 p. 197 - 205
参考文献
Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii), , vol. 33, p. 137 - 138
Zhurnal Neorganicheskoi Khimii, , vol. 33, p. 244 - 246
反应条件
in tetrahydrofuran a suspn. of Rh complex and 9,9'-dichlorobisfluorenyl in THF in 1:1 moleratio was heated at 50°C for 8 h under N2; solvent was removed, residue extd. with hexane to give bisfluorenylidene, residue was extd. with benzene to give RhCl(CO)(PPh3)2, the benzene-insoluble residue was chromd. (Al2O3, CHCl3 eluent) to give RhCl3(CO)(PPh3)2;
参考文献
Journal of Organometallic Chemistry, , vol. 224, # 2 p. 197 - 205
反应条件
triphenylphosphine in chlorobenzene Rh atoms co-codensed with (COCl)2 over 3.5 h, product washed with CH2Cl2, solvent removed in vacuo, solid washed with petroleum ether, dried invacuo, suspended in C6H5Cl and treated with PPh3 in C6H5Cl, mixt. stirred for 90 min at room temp.; soln. filtered into petroleum ether, ppt. washed with petroleum ether and dried in vacuo, product dissolved in hot CH3CN (60°), soln. filtered and cooled, crystals washed with CH3CN and dried in vacuo;
参考文献
Brown, Paul R.; Cloke, F. Geoffrey N.; Green, Malcolm L. H.
Polyhedron, 1985 , vol. 4, p. 869 - 874
