反式-双(三苯基膦)合氯化羰基铑(Ⅰ)合成路线 （共 95 条）
反应条件
triphenylphosphine in not given under N2, the react. of stoich. amt. of Rh-complex and PPh3 at room temp.;
参考文献
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), , p. 1891 - 1898
反应条件
1: methanol; acetone 2: HCl / methanol View Scheme
参考文献
Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii), , vol. 33, p. 137 - 138
Zhurnal Neorganicheskoi Khimii, , vol. 33, p. 244 - 246
反应条件
hydrogen in 1,2,5-trimethyl-benzene atmosphere of synthesis gas (p(H2+CO)=6 atm), 373 K, 2 min;
参考文献
Russian Chemical Bulletin, , vol. 44, # 5 p. 836 - 839
Izvestiya Akademi Nauk, Seriya Khimicheskaya, , # 5 p. 863 - 866
反应条件
triphenylphosphine in acetone byproducts: COD; N2-atmosphere; slow sequential addn. of stoich. amt. of dppe and seven-fold excess of PPh3 to Rh-complex (during 7 h); pptn. after 22 h;
参考文献
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), , p. 120 - 129
反应条件
in benzene byproducts: mercury; refluxing (1 h), cooling to room temp.; solvent removal (vac.), dissolving (CH2Cl2), filration (Celite), chromy. (silica gel, CH2Cl2), recrystn. (EtOH); elem. anal.;
参考文献
Journal of Organometallic Chemistry, , vol. 388, # 3 p. 391 - 408
反应条件
hydrogen in 1,2,5-trimethyl-benzene Kinetics; solvent: mesitylene with N,N-dimethylacetamide (80/20, w/w), atmosphere:synthesis gas (p(H2+CO)=6 atm), 373 K, 2 min;
参考文献
Russian Chemical Bulletin, , vol. 44, # 5 p. 836 - 839
Izvestiya Akademi Nauk, Seriya Khimicheskaya, , # 5 p. 863 - 866
反应条件
in tetrahydrofuran a suspn. of Rh complex and 9,9-dichlorofluorene in THF in 1:2 mole ratio was heated at 55°C for 3.5 h under N2; solvent was removed, residue extd. with light petroleum, bisfluorenylidene was isolated from the ext., extraction residue was RhCl(CO)(PPh3)2;
参考文献
Journal of Organometallic Chemistry, , vol. 224, # 2 p. 197 - 205
反应条件
in tetrahydrofuran byproducts: triphenylphosphine; a soln. of Ph2CCl2 in THF was added under N2 to a suspn. of Rh-complex in the same solvent in 2:1 mole ratio, mixt. was stirred at 60°C for 3.5 h; solvent was removed, residue chromd. over Al2O3 (eluent hexane for Ph2C=CPh2 and CHCl3 for RhCl(CO)(PPh3)2);
参考文献
Journal of Organometallic Chemistry, , vol. 224, # 2 p. 197 - 205
反应条件
in not given byproducts: 2-phenyl-1-methylenecyclopropane; CO-atmosphere (1 atm);
参考文献
Organometallics, , vol. 17, # 21 p. 4532 - 4534
反应条件
in acetone partial dissocn. in soln.; (31)P NMR spectral data;
参考文献
Journal of Organometallic Chemistry, , vol. 322, p. 249 - 256
