反式-双(三苯基膦)合氯化羰基铑(Ⅰ)合成路线 （共 95 条）
反应条件
in ethanol refluxing;
参考文献
Angewandte Chemie - International Edition in English, , vol. 35, # 19 p. 2251 - 2253
反应条件
in chloroform under Ar; Rh complex dissolved in CHCl3;
参考文献
Dalton Transactions, , # 18 p. 3092 - 3100
反应条件
in methanol; dichloromethane Irradiation (UV/VIS); addn. of methanolic soln. of COS to a soln. of Rh(I) complex and P(C6H5)3 in CH2Cl2; filling up with methanol; irradiation (at about 250nm), 30min, stirring; crystn.; react. mechanism discussed;; filtration; washing (CH3OH/ether); drying; concn. of reddish brown filtrate in a flash evaporator at 75°C, reduced pressure; cooling of deep brown soln.; filtration; washing residue with ether; dissoln. in CH2Cl2; repptn.; drying; elem. anal.;;
参考文献
Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical & Analytical, , vol. 20, # 12 p. 1153 - 1155
反应条件
byproducts: P(C6H5)3, PhNO;
参考文献
Inorganica Chimica Acta, , vol. 6, p. 531 - 542
反应条件
byproducts: carbon monoxyde; NMR;
参考文献
Journal of Organometallic Chemistry, , vol. 450, # 1.2 p. 245 - 252
参考文献
Rh: SVol.B2, 2.1.1.5.3, page 102 - 103
反应条件
products not separated;
参考文献
Chemische Berichte, , vol. 117, # 9 p. 2825 - 2838
反应条件
products not separated;
参考文献
Chemische Berichte, , vol. 117, # 9 p. 2825 - 2838
反应条件
products not separated;
参考文献
Chemische Berichte, , vol. 117, # 9 p. 2825 - 2838
反应条件
products not separated;
参考文献
Chemische Berichte, , vol. 117, # 9 p. 2825 - 2838
