in benzene Kinetics; Irradiation (UV/VIS); a soln. of Mo(CO)6 (0.001 M) and excess of the ligand (0.1-0.001 M) in benzene is purged with N2 and flash-photolyzed using a pulsed Nd:YAG laser (353 nm) or ruby laser (347 nm);
参考文献
Kalyanasundaram, K.
Journal of Physical Chemistry, 1988 , vol. 92, # 8 p. 2219 - 2223
1: With sodium carbonate; trans-bis(acetato)bis[o-(di-o-tolylphosphino)benzyl]dipalladium in 1,4-dioxane; water T=165°C; 0.25 h; 2: With hydrogenchloride in 1,4-dioxane; water pH=2;
参考文献
PFIZER PRODUCTS INC.
Patent: WO2008/65508 A1, 2008 ;
Location in patent: Page/Page column 31-32 ;
in Petroleum ether soln. of Mo complex in light petroleum (b.p. 100-120°C) refluxedwith ligand for 16 h under N2; cooled, filtered under N2, cooled to -78.degee.C, ppt. filtered, sepd. by sublimation in vac. (25.deghree.C/0.05 mmHg, 70°C/0.05 mmHg);
参考文献
Hoffmann, Florian; Fester, Gerrit W.; Wagler, Joerg
Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, 2010 , vol. 65, # 9 p. 1137 - 1142
