triphenylphosphine in dichloromethane
Kinetics; byproducts: CO2, (CH3)3N; (N2); at 11.6°C; react. in soln. monitored IR and UV spect.; react. mechanism discussed; not isolated;
参考文献
Shi, Yan-Lung; Gao, Yi-Ci; Shi, Qi-Zhen; Kershner, David L.; Basolo, Fred
Organometallics, 1987 , vol. 6, p. 1528 - 1531
in not given
byproducts: CO2, NH3; NH2OH and PPh3 addn. simultaneously into M(CO)6 soln. at room temp., reaction mixt. allowing to stand for a few h after reaction with NH2OH hascompleted; IR spectroscopic monitoring;
参考文献
Maksakov, V. A.; Ershova, V. A.
Journal of Organometallic Chemistry, 1995 , vol. 485, # 1-2 p. 69 - 78
in acetonitrile
preparation under dry nitrogen; Mo(CO)6 and TMNO were added to acetonitrle giving a yellow solution; PPh3 was added to the mixture; stirring for 16h at room temperature; filtration; filtrate was cooled at -20°C; recrystallization in CHCl3/EtOH; TA, elem. anal.;
参考文献
Hor, T. S. Andy; Chan, Hardy S. O.; Chiam, Caroline S. M.; Lim, Kok Hwa
Thermochimica Acta, 1988 , vol. 128, p. 175 - 184
