in neat (no solvent) on react. of 2.7mmol Na(Co(CO)4) and 2.5mmol (CH3)3SnCl at room temp. under N2;; on evaporization of soln. after 5min, extraction of ppt. with hexane, evaporization of extract and sublimation at 40°C with cooling of receiving part of apparatus (dry ice);;
in benzene byproducts: (CH3)3SiH; reaction for 24 h at 20°C;;
参考文献
Bradley, G. F.; Stobart, S. R.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1974 , p. 264 - 269
Full Text View citing articles Show Details
Gmelin Handbook: Sn: Org.Verb.4, 1.2.1.1.1.4.6, page 17 - 18
Bradley, G. F.; Stobart, S. R.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1974 , p. 264 - 269
Full Text View citing articles Show Details
Gmelin Handbook: Sn: Org.Verb.4, 1.2.1.1.1.4.6, page 17 - 18
