in methanol Kinetics; byproducts: water; in presence or absence of MeO(1-) and Cu(NO3)2, I=0.15, 25°C; not isolated, reaction followed by UV/VIS spectroscopy;
参考文献
Rotondo et al.
Inorganica Chimica Acta, 1978 , vol. 26, p. 189
in methanol Electrochem. Process; Cu anode; working soln.: C11H15NO in MeOH, Et4NClO4 as a conducting additive, at current strength of 40 mA, voltage of 15 V for 1 h at room temp.; ppt. filtered off; recrystd. from EtOH, dried in vac. desiccator; elem. anal.;
in ethanol EtOH soln. of Cu salt added to EtOH soln. of C11H15NO (molar ratio of 1:2), mixt. refluxed for 2 h; on cooling EtOH soln. of CH3ONa added; ppt. filtered off; recrystd. from EtOH; elem. anal.;
in methanol; 1,2-dichloro-ethane Kinetics; byproducts: H2O; an equimolar soln. of Cu(NO3)2*3H2O and salicylaldehydato-ion (1:1) anda soln. of ligand in ClCH2CH2Cl-MeOH (1:1) were warmed to 298°C and mixed; the dependence of the rate constant on concn. of amine was studied; monitored by UV/VIS;
参考文献
Rotondo, Enrico; Priolo, Francesca Cusmano
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1982 , p. 1825 - 1828