1,2-双(二苯基膦基)苯合成路线 （共 27 条）
反应条件
1: bis-diphenylphosphine With cesium hydroxide monohydrate in N,N-dimethyl-formamide T=20°C; 1 h; Molecular sieveInert atmosphere; 2: ortho-dibromobenzene in N,N-dimethyl-formamide T=20°C; 60 h; Inert atmosphereMolecular sieve;
参考文献
Han, Taek Kyu; Ok, Myung Ahn; Chae, Sung Seok; Kang, Sang Ook; Jung, Jae Ho
Patent: US2010/137669 A1, 2010 ;
Location in patent: Page/Page column 11 ;
反应条件
1: chloro-diphenylphosphine With potassium in tetrahydrofuran Heating; 2: ortho-difluorobenzene in tetrahydrofuran; toluene 24 h; Further stages.;
参考文献
Baker, Benjamin A.; Boskovic, Zarko V.; Lipshutz, Bruce H.
Organic Letters, 2008 , vol. 10, # 2 p. 289 - 292
反应条件
trichlorosilane; triethyl phosphite in tetrahydrofuran; toluene T=100°C; 88 h; Inert atmosphere;
参考文献
Polyhedron, , vol. 29, # 1 p. 254 - 261
反应条件
in chloroform Irradiation (UV/VIS); for 2-4 min; UV;
参考文献
Kaltzoglou; Cox; Aslanidis
Inorganica Chimica Acta, 2005 , vol. 358, # 11 p. 3048 - 3056
反应条件
1: 82 percent / (MeCN)2PdCl2 / benzene / 100 h / 70 °C 2: 1.) n-BuLi / 1.) THF, hexane, -78 deg C, 30 min, 2.) THF, hexane, from -78 deg C to RT View Scheme
参考文献
Journal of Organic Chemistry, , vol. 52, # 5 p. 748 - 753
反应条件
1: 1.) Li / 1.) THF, overnight, 2.) THF 2: 82 percent / (MeCN)2PdCl2 / benzene / 100 h / 70 °C 3: 1.) n-BuLi / 1.) THF, hexane, -78 deg C, 30 min, 2.) THF, hexane, from -78 deg C to RT View Scheme
参考文献
Journal of Organic Chemistry, , vol. 52, # 5 p. 748 - 753
反应条件
1: 82 percent / (MeCN)2PdCl2 / benzene / 100 h / 70 °C 2: 1.) n-BuLi / 1.) THF, hexane, -78 deg C, 30 min, 2.) THF, hexane, from -78 deg C to RT View Scheme
参考文献
Journal of Organic Chemistry, , vol. 52, # 5 p. 748 - 753
反应条件
1: 1.) conc. H2SO4, NaNO2, 2.) KI / 1.) water, 10 deg C, 30 min, 2.) water 60 deg C 2: 82 percent / (MeCN)2PdCl2 / benzene / 100 h / 70 °C 3: 1.) n-BuLi / 1.) THF, hexane, -78 deg C, 30 min, 2.) THF, hexane, from -78 deg C to RT View Scheme
参考文献
Journal of Organic Chemistry, , vol. 52, # 5 p. 748 - 753
反应条件
sodium in tetrahydrofuran 1.) -78 deg C to r.t., 2 h, 2.) reflux, 2 h;
参考文献
Bowmaker, Graham A.; Herr, Rudolf; Schmidbaur, Hubert
Chemische Berichte, 1983 , vol. 116, # 11 p. 3567 - 3579
反应条件
in tetrahydrofuran T=60°C; 12 h; Inert atmosphere;
参考文献
Chemistry Letters, , vol. 42, # 2 p. 183 - 185
