Vogt, Matthias; Nerush, Alexander; Iron, Mark A.; Leitus, Gregory; Diskin-Posner, Yael; Shimon, Linda J. W.; Ben-David, Yehoshoa; Milstein, David
Journal of the American Chemical Society, 2013 , vol. 135, # 45 p. 17004 - 17018
potassium tert-butylate T=190°C; 1 h; other temperature, reaction time, effect of cosolvents; various ratios of base and substrate, various amounts of MeOH as cosolvent; Product distribution;
参考文献
Journal of Organic Chemistry, , vol. 63, # 25 p. 9540 - 9544
aluminum oxide; Al2O3+K2CO3+polyethyleneglycol; potassium carbonate T=180°C; other catalyst (K2CO3), other flow rate, reaction with diethyl carbonate in cyclohexane; Product distribution;
参考文献
Tundo, Pietro; Trotta, Francesco; Moraglio, Giovanni
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1989 , p. 1070 - 1071
Selva, Maurizio; Marques, Carlos Alberto; Tundo, Pietro
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1994 , # 10 p. 1323 - 1328
sulfuric acid T=190°C; exchange reaction between (+)-(S)-2-methylbutanoic acid (95percent optical purity) and phenylacetonitrile, optical yield, racemization; stereoselective formation of nitrile by the reaction with chlorosulfonylisocyanate under mild conditions; Product distribution;
