immobilized activated nitrilase in water 30 h; Ambient temperatureeffect of β-cyclodextrin; Rate constant;
参考文献
Fernandes, Bruno C. M.; Mateo, Cesar; Kiziak, Christoph; Chmura, Andrzej; Wacker, Jan; Van Rantwijk, Fred; Stolz, Andreas; Sheldon, Roger A.
Advanced Synthesis and Catalysis, 2006 , vol. 348, # 18 p. 2597 - 2603
potassium tert-butylate T=190°C; 1 h; other temperature, reaction time, effect of cosolvents; various ratios of base and substrate, various amounts of MeOH as cosolvent; Product distribution;
参考文献
Journal of Organic Chemistry, , vol. 63, # 25 p. 9540 - 9544
sulfuric acid T=190°C; exchange reaction between (+)-(S)-2-methylbutanoic acid (95percent optical purity) and phenylacetonitrile, optical yield, racemization; stereoselective formation of nitrile by the reaction with chlorosulfonylisocyanate under mild conditions; Product distribution;
参考文献
Botteghi, C.; Chelucci, G.; Marchetti, M.
Synthetic Communications, 1982 , vol. 12, # 1 p. 25 - 34
T=215°C; P=3040 Torr; other nitriles, other dicarboxylic acids; var. temp. and pressure, conventional and microwave heating; Ea; KineticsThermodynamic dataMechanism;
参考文献
Chemat, Farid; Poux, Martine; Berlan, Jacques
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1994 , # 12 p. 2597 - 2602
