2-苯基-6,7-二氢-1氢-吲哚-4(5氢)-酮合成路线 （共 11 条）
反应条件
ammonia in methanol
T=20°C; Morita-Baylis-Hillman reaction; 0.166667 h;
参考文献
Batchu, Harikrishna; Batra, Sanjay
European Journal of Organic Chemistry, 2012 , # 15 p. 2935 - 2944
反应条件
copper(II) bis(trifluoromethanesulfonate) in 1,2-dichloro-ethane
T=80°C; 8 h;
参考文献
Reddy, B. V. Subba; Reddy, M. Ramana; Rao, Y. Gopal; Yadav; Sridhar
Organic Letters, 2013 , vol. 15, # 3 p. 464 - 467
反应条件
1: 80 percent / molecular sieves 4 Angstroem / tetrahydrofuran / 144 h / 20 °C
2: 65 percent / Pd(PPh3)4; K2CO3; mesityl bromide / dimethylformamide / 2.5 h / 150 °C
View Scheme
参考文献
Aoyagi, Yutaka; Mizusaki, Toshihiko; Shishikura, Masahiro; Komine, Takashi; Yoshinaga, Tokuji; Inaba, Haruko; Ohta, Akihiro; Takeya, Koichi
Tetrahedron, 2006 , vol. 62, # 36 p. 8533 - 8538
反应条件
potassium carbonate in 1,4-dioxane
7 h; Heating;
参考文献
Nitta; Soeda; Iino
Bulletin of the Chemical Society of Japan, 1990 , vol. 63, # 3 p. 932 - 934
反应条件
1.1: 4-(N,N-dimethlyamino)pyridine / tetrahydrofuran; water / 0.33 h / 20 °C
1.2: 12 h
2.1: pyridine / dichloromethane / 0.17 h / 0 °C
2.2: 3 h / 0 - 20 °C
3.1: ammonia / methanol / 0.17 h / 20 °C
View Scheme
参考文献
Batchu, Harikrishna; Batra, Sanjay
European Journal of Organic Chemistry, 2012 , # 15 p. 2935 - 2944
反应条件
1.1: selenium(IV) oxide / 1,4-dioxane; water / 70 °C
2.1: 4-(N,N-dimethlyamino)pyridine / tetrahydrofuran; water / 0.33 h / 20 °C
2.2: 12 h
3.1: pyridine / dichloromethane / 0.17 h / 0 °C
3.2: 3 h / 0 - 20 °C
4.1: ammonia / methanol / 0.17 h / 20 °C
View Scheme
参考文献
Batchu, Harikrishna; Batra, Sanjay
European Journal of Organic Chemistry, 2012 , # 15 p. 2935 - 2944
反应条件
1: 80 percent / molecular sieves 4 Angstroem / tetrahydrofuran / 144 h / 20 °C
2: 65 percent / Pd(PPh3)4; K2CO3; mesityl bromide / dimethylformamide / 2.5 h / 150 °C
View Scheme
参考文献
Aoyagi, Yutaka; Mizusaki, Toshihiko; Shishikura, Masahiro; Komine, Takashi; Yoshinaga, Tokuji; Inaba, Haruko; Ohta, Akihiro; Takeya, Koichi
Tetrahedron, 2006 , vol. 62, # 36 p. 8533 - 8538
反应条件
1: 95 percent / benzene / 4 h
2: 56 percent / potassium carbonate / dioxane / 20 h / Heating; reaction with other α-bromo ketones and α,β-unsaturated ketones
View Scheme
参考文献
Nitta; Soeda; Iino
Bulletin of the Chemical Society of Japan, 1990 , vol. 63, # 3 p. 932 - 934
反应条件
potassium carbonate in 1,4-dioxane
20 h; Heating;
参考文献
Nitta; Soeda; Iino
Bulletin of the Chemical Society of Japan, 1990 , vol. 63, # 3 p. 932 - 934
反应条件
T=100°C; unter Druck;
参考文献
Stetter; Siehnhold
Chemische Berichte, 1955 , vol. 88, p. 271,274
