1: PdCl(C6H4C6H4NH2)(P(C10H15)2C4H9); cesium hydroxide monohydrate; CPME / 24 h / 105 °C / |Sealed tube 2: palladium on activated charcoal; hydrogen / ethanol / 20 °C / 760.05 Torr 3: 1-methoxy-4-chlorobenzene; caesium carbonate; palladium diacetate; dicyclohexyl(2′,6′-dimethoxybiphenyl-2-yl)phosphine / water; tert-butyl alcohol / 16 h / 95 °C View Scheme