(3r,5s)-6-羟基-3,5-o-异-亚丙基-3,5-二羟基己酸乙酯合成路线 （共 4 条）
反应条件
palladium 10 on activated carbon; hydrogen in ethanol T=20°C; P=15201 Torr; 18 h; Autoclave;
参考文献
Wu, Xuri; Wang, Lili; Wang, Shuzhen; Chen, Yijun
Amino Acids, 2010 , vol. 39, # 1 p. 305 - 308
反应条件
1: 78.3 percent / diisobutylaluminium hydride / diethyl ether; toluene / 0.25 h / -70 °C 2: 47.6 percent / SnCl2 / CH2Cl2 / 2 h / 20 °C 3: H2 / Ru[(R)-BINAP]Cl2 / methanol / 1.33 h / 20 °C / 37503 Torr View Scheme
参考文献
Tararov, Vitali I.; Koenig, Gerd; Boerner, Armin
Advanced Synthesis and Catalysis, 2006 , vol. 348, # 18 p. 2633 - 2644
反应条件
1: 47.6 percent / SnCl2 / CH2Cl2 / 2 h / 20 °C 2: H2 / Ru[(R)-BINAP]Cl2 / methanol / 1.33 h / 20 °C / 37503 Torr View Scheme
参考文献
Tararov, Vitali I.; Koenig, Gerd; Boerner, Armin
Advanced Synthesis and Catalysis, 2006 , vol. 348, # 18 p. 2633 - 2644
反应条件
1.1: tetrahydrofuran / 2 h / 20 °C 2.1: Mg powder / tetrahydrofuran / 4 h / Heating 2.2: 82.3 percent / tetrahydrofuran / 20 °C 3.1: H2 / Ru[(R)-BINAP]Cl2 / methanol / 1.33 h / 20 °C / 37503 Torr View Scheme
参考文献
Tararov, Vitali I.; Koenig, Gerd; Boerner, Armin
Advanced Synthesis and Catalysis, 2006 , vol. 348, # 18 p. 2633 - 2644
