铂(2+)氯化物-吡啶(1:2:2)合成路线 （共 28 条）
反应条件
in pyridine Heating under stirring (115°C, N2, 25 min).; Cooling, evapn. to dryness (vacuum), washed (ether, petrol), dried, extraction with acetone, filtn. of TlCl, evapn. to dryness, washed (cold ethanol), recrystn. (acetone/light petroleum, washed (ether/ethanol), elem. anal.;
参考文献
Buxton, David P.; Deacon, Glen B.; Gatehouse, Bryan M; Grayson, Ian L.; Black, David St. C.
Australian Journal of Chemistry, 1988 , vol. 41, # 6 p. 943 - 956
反应条件
in chloroform-d1 byproducts: 2,3-dimethyl-1-butene; isomerization and decomp. in CDCl3;;
参考文献
Cushman, Barry M.; Brown, David B.
Inorganic Chemistry, 1981 , vol. 20, p. 2490 - 2498
反应条件
in pyridine prolonged storing of the soln. in pyridine or on dissolution in excess pyridine;;
参考文献
Chernyaev, I. I.; Gel'man, A. D.
Izv. Plat., 1937 , vol. 14, p. 77 - 121
Full Text Show Details
Gmelin Handbook: Pt: MVol.D, 180, page 396 - 399
反应条件
in chloroform-d1 Irradiation (UV/VIS); Photolysis in the presence of oxygen;;
参考文献
Al-Essa, Razak J.; Ling, Samson S. M.; Puddephatt, Richard J.
Organometallics, 1987 , vol. 6, p. 951 - 959
反应条件
in methanol; water Kinetics; byproducts: CH3SOCH2C6H5; dissolving of trans-((PtCl(C5H5N)2(MeBzSO))(NO3) in water and MeOH; addn. of excess of NaCl; injection of soln. in column every 10 min at 25 and37°C; pptn.;
参考文献
Fontes; Oskarsson; Loevqvist; Farrell
Inorganic Chemistry, 2001 , vol. 40, # 8 p. 1745 - 1750
反应条件
in acetone Pt-complex:pyridine molar ratio was 1:1, 20 °C, 25 h, conversion was 68 percent; monitored by (1)H NMR;
参考文献
De Vekki; Spevak; Skvortsov
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 2001 , vol. 27, # 8 p. 579 - 584
反应条件
in pyridine Heating of Pt complex, and Tl compound in pyridine (N2, 86-115°C, 154 min, stirring).; Cooling , evapn. (high vacuum), washed (light petroleum), dried, extracted (Me2CO), filtn. (leaving TlCl), evapn., washed (cold EtOH), recrystn. (toluene/light petroleum, -28°C, usable for X-ray diffraction).;
参考文献
Buxton, David P.; Deacon, Glen B.; Gatehouse, Bryan M; Grayson, Ian L.; Black, David St. C.
Australian Journal of Chemistry, 1988 , vol. 41, # 6 p. 943 - 956
反应条件
in hydrogenchloride heating of a soln. of (Pt(C5H5N)4)Cl2 with excess concd. HCl soln. in a water bath for several hours under pptn.;;
参考文献
Gmelin Handbook: Pt: MVol.D, 125, page 283 - 285
反应条件
in not given reaction with excess pyridine;;
参考文献
Gmelin Handbook: Pt: MVol.D, 194, page 428 - 431
参考文献
Werner, A.; Fassbender, F.
Z. Anorg. Chem., 1897 , vol. 15, p. 123 - 142
Full Text Show Details
Gmelin Handbook: Pt: MVol.D, 193, page 424 - 427
