铂(2+)氯化物-吡啶(1:2:2)合成路线 （共 28 条）
反应条件
in not given effect of NaCl-soln.;;
参考文献
Drew, H. D. K.; Pinkard, F. W.; Wardlaw, W.; Cox, E. G.
Journal of the Chemical Society, 1932 , p. 988 - 1004
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Gmelin Handbook: Pt: MVol.D, 125, page 283 - 285
反应条件
in not given heating with pyridine for several days on a water-bath;;
参考文献
Cox, E. G.; Saenger, H.; Wardlaw, W.
Journal of the Chemical Society, 1932 , p. 2216 - 2221
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Gmelin Handbook: Pt: MVol.D, 129, page 290 - 292
反应条件
in pyridine reaction in boiling pyridine;;
参考文献
Cox, E. G.; Saenger, H.; Wardlaw, W.
Journal of the Chemical Society, 1932 , p. 2216 - 2221
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Gmelin Handbook: Pt: MVol.D, 129, page 290 - 292
反应条件
in acetone Kinetics; Pt-complex:pyridine molar ratio was 1:10, 20 °C, 32 h, 100 percent conversion; monitored by (1)H NMR, mixt. was extd. with water, water was evapd., residue was washed with CH2Cl2, isolated yield of Ptpy4Cl2 was 43 percent;
参考文献
De Vekki; Spevak; Skvortsov
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 2001 , vol. 27, # 8 p. 579 - 584
反应条件
in dimethyl sulfoxide dissolving of trans-Pt(Py)2Cl2 in dimethylsulfoxide in flask equipped with a refluxer; heating at 80°C for 13 h; cooling; addn. of H2O or Et2O; pptn., filtration, monitoring by NMR; as mixt. of cis- and trans-isomers;
参考文献
De Vekki
Russian Journal of Inorganic Chemistry, 2008 , vol. 53, # 8 p. 1238 - 1241
反应条件
in dichloromethane; acetone addn. of trans-(PtCl2(py)2) to soln. of Pt-complex in CH2Cl2/acetone (2:1), stirring (1 h); evapn. to dryness, washing (diethyl ether, 2.product solid), evapn. of washings to dryness, treatment with i-PrOH/hexane;
参考文献
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), , p. 1011 - 1016
反应条件
in further solvent(s) dissolving of trans-Pt(Py)2Cl2 in diethylsulfoxide in flask equipped with a refluxer; heating at 70-100°C for 16 h; cooling; addn. of H2O or Et2O; pptn., filtration, monitoring by NMR;
参考文献
De Vekki
Russian Journal of Inorganic Chemistry, 2008 , vol. 53, # 8 p. 1238 - 1241
反应条件
lithium triethylborohydride in tetrahydrofuran
byproducts: LiCl, B(C2H5)3, H2; 23°C, 2 h; Washing with H2O to separate alkali halogenide from metal powder.;
参考文献
Boennemann, Helmut; Brijoux, Werner; Joussen, Thomas
Angewandte Chemie, 1990 , vol. 102, p. 324 - 326
